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Chem. Soc. Rev.最新综述:用于太阳能光解水的钒酸铋光电极的研究进展
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最新一期的Chem. Soc. Rev.刊发了题为Progress in bismuth vanadate photoanodes for use in solar water oxidation的综述,详细的总结了钒酸铋这种经典光电催化材料在光解水领域的研究进展。文章16页,引文106篇。 Harvesting energy directly from sunlight as nature accomplishes through photosynthesis is a very attractive and desirable way to solve the energy challenge. Many efforts have been made to find appropriate materials and systems that can utilize solar energy to produce chemical fuels. One of the most viable options is the construction of a photoelectrochemical cell that can reduce water to H2 or CO2 to carbon-based molecules. Bismuth vanadate (BiVO4) has recently emerged as a promising material for use as a photoanode that oxidizes water to O2 in these cells. Significant advancement in the understanding and construction of efficient BiVO4-based photoanode systems has been made within a short period of time owing to various newly developed ideas and approaches. In this review, the crystal and electronic structures that are closely related to the photoelectrochemical properties of BiVO4 are described first, and the photoelectrochemical properties and limitations of BiVO4 are examined. Subsequently, the latest efforts toward addressing these limitations in order to improve the performances of BiVO4-based photoanodes are discussed. These efforts include morphology control, formation of composite structures, composition tuning, and coupling oxygen evolution catalysts. The discussions and insights provided in this review reflect the most recent approaches and directions for general photoelectrode developments and they will be directly applicable for the understanding and improvement of other photoelectrode systems. . GA.gif [ 来自科研家族 材料家族 ] |
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2012-10-27 11:29:07, 2.43 M
» 收录本帖的淘帖专辑推荐
万卷阁 | 纳米材料、介孔材料综述文献 | 纳米化学/电化学综述 | nano physics&chem |
光催化专辑 | 材料类精品资源 | 纳米结构太阳能转换专辑 | 光催化&好帖 |
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材料相关文献 | 海外留学经验及留学办理等相关事宜的收录 | 化学镀,分子印迹学,电化学,功能材料。。。 |
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