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Acc. Chem. Res.最新综述：石墨的去结构化---“石墨化物”溶液
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最新一期的Acc. Chem. Res.刊发了题为Deconstructing Graphite: Graphenide Solutions的最新综述，介绍了由石墨为前驱物，通过液相剥离、插层等方法形成含有石墨薄片的溶液或分散液。文章9页，引文68篇。 Growing interest in graphene over past few years has prompted researchers to find new routes for producing this material other than mechanical exfoliation or growth from silicon carbide. Chemical vapor deposition on metallic substrates now allows researchers to produce continuous graphene films over large areas. In parallel, researchers will need liquid, large scale, formulations of graphene to produce functional graphene materials that take advantage of graphene’s mechanical, electrical, and barrier properties. In this Account, we describe methods for creating graphene solutions from graphite. Graphite provides a cheap source of carbon, but graphite is insoluble. With extensive sonication, it can be dispersed in organic solvents or water with adequate additives. Nevertheless, this process usually creates cracks and defects in the graphite. On the other hand, graphite intercalation compounds (GICs) provide a means to dissolve rather than disperse graphite. GICS can be obtained through the reaction of alkali metals with graphite. These compounds are a source of graphenide salts and also serve as an excellent electronic model of graphene due to the decoupling between graphene layers. The graphenide macroions, negatively charged graphene sheets, form supple two-dimensional polyelectrolytes that spontaneously dissolve in some organic solvents. The entropic gain from the dissolution of counterions and the increased degrees of freedom of graphene in solution drives this process. Notably, we can obtain graphenide solutions in easily processable solvents with low boiling points such as tetrahydrofuran or cyclopentylmethylether. We performed a statistical analysis of high resolution transmission electronic micrographs of graphene sheets deposited on grids from GICs solution to show that the dissolved material has been fully exfoliated. The thickness distribution peaks with single layers and includes a few double- or triple-layer objects. Light scattering analysis of the solutions shows the presence of two-dimensional objects. The typical size of the dissolved flakes can be determined by either static or dynamic light scattering (DLS) using models available in the literature for disk-shape objects. A mean lateral size of ca. 1 μm is typically observed. We also used DLS to monitor the reaggregation that occurs as these sensitive solutions are exposed to air. The graphenide solutions reported in this Account can be used to deposit random arrays of graphene flakes and large single flakes of a lateral size of tens of micrometers onto different substrates. Using the graphenide solutions described in this Account, we foresee the large-scale production of graphene-based printings, coatings, and composites. .  ar-2012-00141s_0006.gif [ 来自科研家族 材料家族 ] |
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2012-10-26 12:00:53, 1.28 M
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