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Chem. Soc. Rev.最新综述：Pt-Pd双金属催化剂的增强催化/电催化性能
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最新一期的Chem. Soc. Rev.刊发了由美国佐治亚理工大学的大牛夏幼南教授课题组撰写的题为Enhancing the catalytic and electrocatalytic properties of Pt-based catalysts by forming bimetallic nanocrystals with Pd的综述，详细的总结了增强Pt-Pd双金属催化剂催化/电催化性能这方面的工作进展。文章15页，引文66篇。 Bimetallic nanocrystals consisting of two distinct metals such as Pd and Pt are attractive for a wide variety of catalytic and electrocatalytic applications as they can exhibit not only a combination of the properties associated with both metals but also enhancement or synergy due to a strong coupling between the two metals. With Pd as the base metal, many methods have recently been demonstrated for the synthesis of Pd–Pt bimetallic nanocrystals having a wide variety of different structures in the form of alloys, dendrites, core–shells, multi-shells, and monolayers. In this tutorial review, we begin with a brief discussion on the possible structures of Pd–Pt bimetallic nanocrystals, followed by an account of recent progress on synthetic approaches to such nanocrystals with controlled structures, shapes and sizes. In addition to the experimental procedures and mechanistic studies, a number of examples are presented to highlight the use of such bimetallic nanocrystals as catalysts or electrocatalysts for various applications with enhanced performance relative to their monometallic counterparts. .  GA.gif [ 来自科研家族 材料家族 ] |
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2012-10-21 13:51:41, 5.13 M
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