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lot100
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[交流]
请求帮忙查查 7751-38-4
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请高手帮忙查查 Dichlorodiisopropylsilane 7751-38-4的合成资料！谢谢！ 有参考Beilstein 4(4)4171！ 谢谢！！ |
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woodcool
木虫 (小有名气)
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4楼2007-06-21 11:28:13
zyy816
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lot100(金币+1):还是谢谢！虽然这篇文献我已经有了！
lot100(金币+1):还是谢谢！虽然这篇文献我已经有了！
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Bibliographic Information Versatile method for introduction of bulky substituents to alkoxychlorosilanes. Masaoka, Shin; Banno, Tadashi; Ishikawa, Mitsuo. Hokko Chemical Industry Co., Ltd., Muneage 402, Tamano, Okayama, Japan. Journal of Organometallic Chemistry (2006), 691(1-2), 182-192. Publisher: Elsevier B.V., CODEN: JORCAI ISSN: 0022-328X. Journal written in English. CAN 144:192298 AN 2005:1300600 CAPLUS Abstract Reactions of various alkoxytrichlorosilanes prepd. in situ from tetrachlorosilane and alcs., with Grignard reagents bearing a bulky substituent such as the iso-Pr, sec-Bu, and cyclohexyl group afforded triisopropyl-, tri(sec-butyl)-, and tricyclohexylalkoxysilane in high yields. The reactions of n-butoxytrichlorosilane with these Grignard reagents produced triisopropyl-, tri(sec-butyl)-, and tricyclohexyl(n-butoxy)silane in 94%, 96%, and 92% yields, resp. Methoxymethyldichlorosilane reacted with the same Grignard reagents to give diisopropyl-, di(sec-butyl)-, and dicyclohexylmethoxymethylsilane in 84%, 83%, and 83% yields. Treatment of methoxydimethylchlorosilane with the Grignard reagents readily afforded isopropyl-, sec-butyl-, and cyclohexylmethoxydimethylsilane in excellent yields. Similar treatment of methoxydimethylchlorosilane with tert-butylmagnesium chloride gave tert-butylmethoxydimethylsilane in 62% yield. |
2楼2007-06-21 00:25:25
zyy816
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lot100(金币+3):谢谢！
lot100(金币+3):谢谢！
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Bibliographic Information Procedure for production of halotriorganosilane and dihalodiorganosilane. Winterfeld, Joern; Abele, Bors Cajus; Stenzel, Oleg T. (Wacker-Chemie G.m.b.H., Germany). Ger. (2000), 6 pp. CODEN: GWXXAW DE 19919152 C1 20000504 Patent written in German. Application: DE 99-19919152 19990427. Priority: . CAN 132:279350 AN 2000:289182 CAPLUS Patent Family Information Patent No. Kind Date Application No. Date DE 19919152 C1 20000504 DE 1999-19919152 19990427 WO 2000064909 A1 20001102 WO 2000-EP3088 20000406 W: CA, CN, HU, JP, US RW: AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE EP 1173446 A1 20020123 EP 2000-917052 20000406 R: AT, BE, CH, DE, DK, ES, FR, GB, GR, IT, LI, LU, NL, SE, MC, PT, IE, FI HU 200200944 A2 20020729 HU 2002-944 20000406 Priority Application DE 1999-19919152 A 19990427 WO 2000-EP3088 W 20000406 Abstract Procedures for the prodn. of organochlorsilanes, R4-cSiXc by reaction of hydrogen halide with silanes R4-a-bSiHaXb (R = hydrocarbyl, X = halo, a, b, c = 1-2), in presence of Lewis acid catalyst is described. |
3楼2007-06-21 00:26:01
lot100 
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5楼2007-06-21 11:39:25
