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[资源] 选择性氧化催化剂的文献

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选择性氧化催化剂经典文献

Genesis of siteisolationand phasecooperation
in selectiveoxidation catalysis
RobertKarlGrasselli
Departments ofChemical Engineering and Materials Science, University ofDelaware, Newark, DE19716, USAand
Institute ofPhysical Chemistry, University ofMunich, Butenandtstrasse 5-13, D-81377 Munich, Germany
Twooftheimportantprinciples governing selective oxidation catalysis aresiteisolation andphasecooperation. Theyarediscussedhere
in light of their inception, development, historic perspective and current acceptance in the field of selective oxidation and ammoxidation
catalysis.
KEY WORDS: site isolation; phase cooperation; oxidation; ammoxidation; propylene; acrolein; acrylonitrile; molybdates; antimonates

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Fundamental principles of selective heterogeneous oxidation catalysis
Robert Karl Grasselli
DepartmentsofChemicalEngineeringandMaterialsScience,UniversityofDelaware,Newark,DE19716,USAandInstituteofPhysicalChemistry,
University of Munich, Butenandtstrasse 5-13, D-81377 Munich, Germany
Seven principles (‘‘seven pillars’’) underpinning selective heterogeneous oxidation catalysis, comprising lattice oxygen, metal–
oxygen bond strength, host structure, redox, multifunctionality of active sites, site isolation, and phase cooperation are described.
Their intended utilization towards a deeper understanding of metal oxide catalyst behavior and application towards catalyst design
are indicated.
KEY WORDS: lattice oxygen; metal–oxygen bond; host structure; redox; multifunctionality; site isolation; phase cooperation;
oxidation; ammoxidation; acrolein; acrylonitrile; molybdates; antimonates

http://www.divshare.com/download/844689-070

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[ Last edited by rabbit7708 on 2007-6-20 at 13:22 ]

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