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[交流] Nature——semiconducting polymers——Blom

Blom 大作

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abstract

Electron transport in semiconducting polymers is usually inferior to hole transport, which is ascribed to charge trapping on isolated defect sites situated within the energy bandgap. However, a general understanding of the origin of these omnipresent
charge traps, as well as their energetic position, distribution and concentration, is lacking. Here we investigate electron transport in a wide range of semiconducting polymers by current–voltage measurements of single-carrier devices. We observe for this materials class that electron transport is limited by traps that exhibit a Gaussian energy distribution in the bandgap. Remarkably, the electron-trap distribution is identical for all polymers considered: the number of traps amounts to 3×10^23 traps per m3 centred at an energy of 3.6 eV below the vacuum level, with a typical distribution width of 0.1 eV. This indicates that the electron traps have a common origin that, we suggest, is most likely related to hydrated oxygen complexes.
A consequence of this finding is that the trap-limited electron current can be predicted for any polymer.
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