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[资源] Handbook on the Physics and Chemistry V15-17

以前发国该丛书的第一到第四卷,见帖子
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今天发15到17卷



Handbook on the Physics and Chemistry of Rare Earths, Volume 17 : Lanthanides/Actinides: Physics - I


By

Publisher:   North Holland
Number Of Pages:   788
Publication Date:   1993-11-01
Sales Rank:   3414686
ISBN / ASIN:   0444815023
EAN:   9780444815026
Binding:   Hardcover
Manufacturer:   North Holland
Studio:   North Holland
Average Rating:  
Total Reviews:  



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Book Description:

This volume of the Handbook is the first of a three volume set of reviews devoted to the interrelationships, similarities, differences and contrasts of the lanthanide and actinide series of elements. In order to comprehensively cover this large field two leading scientists, G.H. Lander and G.R. Choppin, were invited to be guest editors for this special set of volumes. Together, the four editors carefully and critically chose the various topics and invited the appropriate experts to write reviews keeping in mind that the emphasis was to be on the interrelationships of the lanthanides and actinides. The volume contains eight chapters concerned with some of the physical aspects of the lanthanide and actinide series. The first three chapters are theoretical in nature and the last five are more heavily oriented towards experimental studies.
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Handbook on the Physics and Chemistry of Rare Earths : Volume 16  

By

Publisher:   North Holland
Number Of Pages:   604
Publication Date:   1993-07-01
Sales Rank:   4103188
ISBN / ASIN:   0444897828
EAN:   9780444897824
Binding:   Hardcover
Manufacturer:   North Holland
Studio:   North Holland
Average Rating:  
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Book Description:

The first chapter focuses on one aspect of one of the most stimulating topics in the whole of lanthanide science: the dual valence state elements Ce, Pr and Tb (valences of 3 and 4) and Sm, Eu, Tm and Yb (valences of 2 and 3). The authors bring us up to date on the status of our knowledge of valence fluctuation and heavy fermion 4f systems as gleaned from neutron scattering experiments. The major topics include cerium-based valence fluctuation systems, cerium-based heavy fermion materials and ytterbium-based materials. The remaining quarter of the chapter deals with samarium-, europium- and thulium-based systems.


The next chapter deals with the thermal conductivity of rare earth containing materials and is the first major review on this topic. A great deal of information can be obtained on the electrical and magnetic nature of these solids, because of the varied response of the thermal conductivity to long range magnetic order, spin glass behavior, heavy fermions and Kondo lattices, crystalline electric fields, and superconductivity in metallic systems. The thermal conductivity of insulators and semiconductors is also reviewed.


The third and fourth chapters deal with special classes of materials rather than measuring techniques as found in the first two chapters and the last one of this volume. The authors discuss the chemistry, structure, electrical, magnetic and thermal behaviors, spectroscopic (vibrational, ultraviolet-visible and Mössbauer) properties, and luminescence of pyrochlores.


The longest chapter in this book deals with the crystal structures of approximately 100 of the ˜225 known minerals. These minerals were grouped into five classes based on the types of anionic groups found in the various structures. Within each class the minerals are arranged by the sizes of the anionic groups (isolated groups, chains, sheets or plates, and three-dimensional frameworks). The chapter is well illustrated with drawings of the structures and anion coordination polyhedra around the rare earth ion.


The last chapter is concerned with appearance potential spectroscopy (APS), which measures the probability for electronic excitation of a core level as a function of the incident electron energy. This is a technique which in the future may be accepted as a popular analytical tool for the material characterization of surfaces.

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Handbook on the Physics and Chemistry of Rare Earths : Volume 15

By

Publisher:   North Holland
Number Of Pages:   530
Publication Date:   1991-11-01
Sales Rank:  
ISBN / ASIN:   0444889663
EAN:   9780444889669
Binding:   Hardcover
Manufacturer:   North Holland
Studio:   North Holland
Average Rating:  
Total Reviews:  



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Book Description:

Volume 15 in this series continues the voyage of discovery started almost a decade ago.

Chapter 98 adds significantly to an evaluation of systematic, experimental low-temperature studies of the ambivalent behaviours of cerium (ferromagnetism, antiferromagnetism, spin glass, superconductivity etc.) which depend upon its environment in materials. The conclusions arrived at should provide new data against which the theory can be advanced.

The next chapter provides a review of rare earth carbides, emphasizing the thermodynamics, phase diagrams, crystal structures and physical properties. The binary rare earth carbides present an exceptionally wide range of compositions and structures both as solids and gas-phase molecules. Complex carbides with additional metal and non-metal components also receive attention.

Metal-rich halides (i.e. compounds with an X/R ratio <2) are the subject of the next chapter. The compounds are classified according to their structure and chemical bonding characteristics and their electrical and magnetic properties are also reviewed.

Chapter 101 deals with the preparation, structure, chemical and physical properties of heavy-metal fluoride glasses. Large amounts of rare earths can be added into these, and they possess a great potential for optical applications in the mid-infrared range as fiber optic glasses for communication and transmission of information, optical wave guides, fiber lasers and sensors.

The following chapter explores the chemical kinetics of solvent and ligand exchange in aqueous lanthanide solutions. A wealth of tabulated information on rate and equilibrium constants is provided in textual and tabular form. Chapter 103 considers the fundamentally important reactions of the lanthanide ions with water. These interactions are discussed for both solids and solutions. The hydrated species are considered in detail for the aqueous solution, revealing the consequences of the lanthanide series sequence.

The concluding chapter reviews macrocyclic complexes formed by rare earth and dioxouranium ions as templates. Synthetic trends and reactivity are considered as well as potential uses of these intriguing wrap-around structures.


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