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[资源] Lanthanides and Actinides in Ionic Liquids

Lanthanides and Actinides in Ionic Liquids
Koen Binnemans
Contents
1. Introduction 1
2. Solvation and Solubility 3
2.1. Solvation 3
2.2. Solubility 5
2.3. Lanthanide Complexes as Major Ionic Liquid Components 6
2.4. Bis(trifluoromethylsulfonyl)imide Complexes 6
3. Spectroscopic Properties 7
3.1. Trivalent Lanthanide Ions 7
3.2. Divalent Lanthanide Ions 8
3.3. Uranium 8
3.4. Other Actinides 9
4. Redox Behavior and Electrodeposition of Metals 9
4.1. Redox Behavior of Lanthanides 9
4.2. Redox Behavior of Uranium 9
4.3. Redox Behavior of the Other Actinides 10
4.4. Electrodeposition 10
5. Solvent Extraction 11
6. Treatment of Spent Nuclear Fuel 12
7. Lanthanide-Mediated Organic Reactions 14
7.1. C-C Bond Formation 14
7.1.1. Friedel-Crafts Reactions 14
7.1.2. Diels-Alder Reactions 15
7.1.3. Other C-C Bond-Forming Reactions 16
7.2. C-X Bond Formation 18
7.3. Oxidation and Reduction Reactions 18
7.4. Polymerization Reactions 19
8. Applications in Materials Sciences 19
9. Conclusions and Outlook 20
10. Abbreviations 20
11. Acknowledgment 20
12. Note Added in Proof 20
13. References 21
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