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[资源] 又一篇关于不对称催化的Chemical Reviews

Contents
1. Introduction and Scope 1
2. Solvent-Free and Highly Concentrated Reactions
in Asymmetric Catalysis
3
2.1. Epoxide-Opening Reactions 3
2.1.1. Desymmetrization of meso-Epoxides 3
2.1.2. Mechanistic Investigations and
Implications for Solvent-Free Epoxide
Opening
4
2.1.3. ARO of meso-Epoxides with Benzoic Acid 5
2.2. Reactions with Racemic Epoxides 5
2.2.1. Kinetic Resolution of Epoxides with
Me3SiN3
5
2.2.2. Dynamic Kinetic Resolution of
Epichlorohydrin
6
2.2.3. Hydrolytic Kinetic Resolution of Epoxides 7
2.2.4. Oligomeric (salen)Co(III) Catalysts for the
HKR
8
2.2.5. Supported (salen)Co(III) Catalyst for the
HKR
11
2.2.6. Asymmetric Ring Opening of Epoxides
Using Carbon Dioxide
11
2.3. Asymmetric Hetero-Diels-Alder Reaction 12
2.3.1. Asymmetric Hetero-Diels-Alder Reaction
of Danishefsky’s Diene and Aldehydes
13
2.3.2. Hetero-Diels-Alder Reaction Catalyzed by
(salen)Cr(X) Complexes
14
2.3.3. Organocatalytic Hetero-Diels-Alder
Reaction Catalyzed by TADDOL
Derivatives
15
2.3.4. Diastereoselective Hetero-Diels-Alder
Reaction
15
2.3.5. Asymmetric Hetero-Diels-Alder Reaction
of Danishefsky’s Diene with N-Aryl Imines
16
2.3.6. Asymmetric Hetero-Diels-Alder Reaction
of Brassard’s Diene and Aldehydes
17
2.3.7. Asymmetric Hetero-Diels-Alder Reaction
of Mono-oxygenated Dienes and
Aldehydes
17
2.4. Asymmetric Metathesis Reactions 19
2.4.1. Asymmetric Ring-Closing Metathesis
Reactions
19
2.4.2. Asymmetric Ring-Opening Metathesis/
Cross-Metathesis Reactions
20
2.5. Asymmetric Carbonyl-Ene Reaction 20
2.5.1. Self-Supported (BINOLate)Ti-Based
Catalysts for the Carbonyl-Ene Reaction
21
2.6. Asymmetric Addition of Organometallic
Reagents to Aldehydes and Ketones
21
2.6.1. Enantioselective Alkylation of Aldehydes
with Dialkylzinc Reagents
21
2.6.2. Catalytic Asymmetric Acetylide Additions
to Aldehydes
23
2.6.3. Asymmetric Addition of Alkyl Groups to
Ketones
23
2.6.4. Asymmetric Allylation of Ketones 27
2.7. Lewis Acid Catalyzed Asymmetric Michael
Reactions
29
2.8. Asymmetric Friedel-Crafts with Aromatic
Ethers
29
2.9. Asymmetric Pauson-Khand-Type Reaction 30
2.10. Asymmetric Hydroformylation 31
2.10.1. Heterogeneous Asymmetric
Hydroformylation Reactions
32
2.11. Asymmetric Hydrogenation Reaction 33
2.12. Asymmetric Hydrosilylation of Ketones 34
2.13. Asymmetric Allylic Amination 35
2.14. Asymmetric Conjugate Addition of Cyanide to
R,‚-Unsaturated Imides
35
2.15. Asymmetric Organocatalytic Reactions 36
2.15.1. Asymmetric Hajos-Parrish Reaction 36
2.15.2. Enantioselective Aldol Reaction 37
2.15.3. Enantioselective Morita-Baylis-Hillman
Reaction
37
2.15.4. Enantioselective Organocatalytic
Conjugate Additions
38
2.15.5. R-Amination of Ketones 39
3. Outlook 39
4. Abbreviations 39
5. Acknowledgments 40
6. References 40

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