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杨大松至尊木虫 (文坛精英)
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[求助]
求助微谱数据，谢谢
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碳谱数据如下： 56.2,56.7,64.9,65.0,71.5,74.7,75.1,77.7,101.7,104.0,106.9,108.0,120.2,140.7,148.3,151.8,154.6,166.5 辛苦各位了，谢谢。 |
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火箭穿屁屁
木虫 (正式写手)
地球球长
- 应助: 197 (高中生)
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- 虫号: 407719
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- 专业: 天然药物化学
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
jiangchunyong: 金币+1, 谢谢 2012-08-22 09:21:27
杨大松: 金币+15, ★★★★★最佳答案 2012-08-22 09:57:37
感谢参与，应助指数 +1
jiangchunyong: 金币+1, 谢谢 2012-08-22 09:21:27
杨大松: 金币+15, ★★★★★最佳答案 2012-08-22 09:57:37
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查询结果：共查到140个化合物(查询结果仅供参考) -------------------------------------------------------------------------------- 1 . 4-hydroxy-3-methoxyphenol-β-D-[6-O-(4-hydroxy-3,5-dimethoxylbenzoate)]glucopyranoside 相似度:84.2% China Journal of Chinese Materia Medica 2010 35 1261-1271 Chemical constituents of stems and branches of Adina polycephala ZHANG Yanling; GAN Maoluo; LI Shuai; WANG Sujuan; ZHU Chenggen; YANG Yongchun; HU Jinfeng; CHEN Naihong; SHI Jiangong Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 2 . euosmoside A C21H24O11 相似度:76.1% Journal of Asian Natural Products Research 2006 8 411-415 Two new phenyl esters from Litsea euosma Y. XIAO, J.-F. ZHAO, X.-D. YANG, G.-P. LI, J.-H. YANG, H.-B. ZHANG and L. LI Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 3 . canthoside D C18H26O12 相似度:72.2% Phytochemistry 2002 61 461-464 Iridoid and phenolic diglycosides from Canthium berberidifolium Tripetch Kanchanapoom, Ryoji Kasai, Kazuo Yamasaki Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 4 . 6'-O-vanilloylisotachioside C21H24O11 相似度:71.4% Planta Medica 2007 73 1415-1417 Bioactive Phenols from the Leaves of Baccaurea ramiflora Xian-Wen Yang,Jun-Song Wang ,Yan-Lin Ma ,Hai-Tao Xiao ,Yi-Qing Zuo , Hua Lin , Hong-Ping He , Ling Li , Xiao-Jiang Hao Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 5 . 2-Methoxy-1, 4-biphenol-1-O-[ 6-O-(3-methoxy-4-hydroxybenzoyl) ]-β-D-glucopyranoside C21H24O11 相似度:71.4% Acta Botanica Yunnanica 2009 31(3) 284-288 Phenolic Constituents from the Fruits of Amomum tsao2ko (Zingiberaceae) WANGWei,YANG Chong-Ren,ZHANG Ying-Jun Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 6 . euosmoside B C22H26O12 相似度:68.1% Journal of Asian Natural Products Research 2006 8 411-415 Two new phenyl esters from Litsea euosma Y. XIAO, J.-F. ZHAO, X.-D. YANG, G.-P. LI, J.-H. YANG, H.-B. ZHANG and L. LI Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 7 . capparoside A C18H26O12 相似度:66.6% Journal of Natural Products 2009 72 1954-1959 Antiestrogenic Constituents of the Thai Medicinal Plants Capparis flaWicans and Vitex glabrata Prathan Luecha, Kaoru Umehara, Toshio Miyase, and Hiroshi Noguchi Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 8 . 3-methoxy-4-hydroxyphenol 1-O-β-D-(6'-O-galloyl)glucopyranoside C20H22O12 相似度:66.6% Phytochemistry 1987 26 1147-1152 Phenolic glucoside gallates from quercus mongolica and q. acutissima Kanji Ishimaru,Gen-Ichiro Nonaka,Itsuo Nishioka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 9 . clemaparviloside B C21H24O11 相似度:66.6% Acta Pharmaceutica Sinica 2010 45 1527-1532 Two new phenolic glycosides from the stems of Clematis parviloba YAN Li-hua, XU Li-zhen *, WANG Zhi-min, ZHANG Qi-wei, YANG Shi-lin* Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 10 . 1,4,8-trihydroxynaphthalenyl 1-O-β-D-[6'-O-(3'',5''-dimethoxy-4''-hydroxybenzoyl)]glucopyranoside C25H26O12 相似度:63.6% Journal of Natural Products 1996 59 159-160 New Naphthalenyl Glucosides from the Roots of Juglans mandshurica Yoon-Ki Joe and Jong-Keun Son Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 11 . 3-O-β-D-[6'-(4''-Hydroxy-3'',5''-dimethyoxybenzoyl)]glucopyranosylg-pyranone 相似度:63.1% Pharmazie 2006 61 474-477 γ-Pyranone derivatives and other constituents from Erigeron annuus Xin Li, Jing Pan and Kun Gao Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 12 . alpinoside A C22H26O12 相似度:61.9% Acta Pharmaceutica Sinica 2006 Vol 41 233-235 A new glycoside from Alpinia officinarum AN Ning; LIN Jia; YANG Shi-lin; ZOU Zhong-mei; XU Li-zhen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 13 . Walsuraside C21H24O12 相似度:61.1% Chemistry & Biodiversity 2006 Vol. 3 224 New Antioxidant Phenolic Glycosides from Walsura yunnanensis Xiao-Dong Luo, Da-Gang Wu, Xiang-Hai Cai, and Edward J. Kennelly Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 14 . 3,4-dimethoxyphenyl-O-β-D-glucopyranoside 相似度:61.1% Natural Product Research 2008 22 483-488 Two new phenolic water-soluble constituents from branch bark of Davidia involucrata Zu-Jian Wu; Ming-An Ouyang; Shi-Bin Wang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 15 . isotachioside 相似度:61.1% Phytochemistry 1999 52 917-921 Two saponins from Pteleopsis hylodendron F.N. Ngounou, Atta-ur-Rahman, M. Iqbal Choudhary, Shahid Malik, Seema Zareen, Riaz Ali, D. Lontsi, B.L. Sondengam Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 16 . 4-hydroxy-2-methoxyphenol 1-O-β-(6'-O-galloyl)glucoside C20H22O12 相似度:61.1% Phytochemistry 1989 28 2443-2446 Phenol glucoside gallates from Mallotus japonicus Reiko Saijo,Gen-ichiro Nonaka,Itsuo Nishioka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 17 . 4'-hydroxy-2',6'-dimethoxyphenol 1-O-β-D-(6-O-syringoyl) glucopyranoside C23H28O1 相似度:61.1% Journal of Natural Medicines 2009 63 220-222 A new phenolic glycoside syringate from the bark of Juglans mandshurica MAXIM. var. sieboldiana MAKINO Koichi Machida, Yukiko Yogiashi, Sakiko Matsuda, Aiko Suzuki and Masao Kikuchi Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 18 . 6'-O-(3-(2-(Hydroxymethyl)acryloyloxy)-2-methylpropanoyl)arbutin C20H26O11 相似度:61.1% Natural Product Communications 2008 3 57-64 Bisresorcinols and Arbutin Derivatives fromGrevillea banksii R. Br. Hao Wang, David Leach, Michael C. Thomas, Stephen J. Blanksby, Paul I. Forster andPeter G. Waterman Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 19 . 2,4-dimethoxyphenyl 1-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside C19H28O12 相似度:57.8% Chemical & Pharmaceutical Bulletin 2006 54(1) 14-20 Constituents from the Bark of Tabebuia impetiginosa Tsutomu WARASHINA,Yoshimi NAGATANI,and Tadataka NORO Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 20 . 3,4-Dimethoxyphenol β-D-apiofuranosyl(1→6)-β-D-glucopyranoside C19H28O12 相似度:57.8% Chemical & Pharmaceutical Bulletin 2005 53(1) 110-113 New Phenolics from the Roots of Symplocos caudata WALL JianShuang JIANG, ZiMing FENG, YingHong WANG, and PeiCheng ZHANG Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 21 . robustaside 相似度:57.8% Guihaia 2010 30 884-886 Chemical constituents from the leaf of Helicia tsaii WU Ying-Rui, ZHAO You-Xing, ZHOU Jun Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 22 . 4'-hydroxy-3'-methoxy-phenol-β-D-[6-O-(4''-hydroxy-3'',5''-dimethoxy-benzoate)]glucopyranoside 相似度:57.8% Acta Pharmaceutica Sinica 2010 45 1527-1532 Two new phenolic glycosides from the stems of Clematis parviloba YAN Li-hua, XU Li-zhen *, WANG Zhi-min, ZHANG Qi-wei, YANG Shi-lin * Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 23 . rashomoside B C22H25O13 相似度:57.8% Journal of Natural Medicines 2011 65 385-390 New phenolic compounds from Meehania urticifolia Toshihiro Murata ,Toshio Miyase ,Fumihiko Yoshizaki Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 24 . 4-hydroxymethyl-2-methoxyphenyl 1-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside C19H28O12 相似度:55.5% Phytochemistry 2005 66 589-597 Further constituents from the bark of Tabebuia impetiginosa Tsutomu Warashina, Yoshimi Nagatani, Tadataka Noro Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 25 . 4-hydroxyphenyl 6-O-[(3R)-3,4-dihydroxy-2-methylenebutanoyl]-β-D-glucopyranoside C17H22O10 相似度:55.5% Journal of Natural Products 1997 60 620-622 A New Glycoside Antimicrobial Agent from Persoonia linearis pinifolia John K. MacLeod, Hasse B. Rasmussen, and Anthony C. Willis Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 26 . ethyl O-β-(6'-galloyl)-glucopyranoside C15H20O10 相似度:55.5% Planta Medica 2008 74 445-448 Chemical Constituents from the Stem Bark of Trewia nudiflora L. and their Antioxidant Activities Qian-jin Kang, Xian-wen Yang, Shao-huaWu1,Yan-ling Ma, Ling Li, Yue-mao Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 27 . 1-O-galloyl-6-O-(4-hydroxy-3,5-dimethoxy)benzoyl-β-D-glucose C22H24O14 相似度:55.5% Planta Medica 2001 67 370-371 1-O-Galloyl-6-O-(4-hydroxy-3,5-dimethoxy)benzoyl-β-D-glucose, a New Hepatoprotective Constituent from Combretum quadrangulare I Ketut Adnyana, Yasuhiro Tezuka, Suresh Awale,Arjun H. Banskota, Kim Qui Tran, Shigetoshi Kadota Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 28 . 3,4-dimetoxyphenyl-1-O-β-(6-sulpho)-glucopyranoside C14H20O11S 相似度:55.5% Phytochemistry 2009 70 641-649 Phenolic compounds from Bursera simaruba Sarg. bark: Phytochemical investigation and quantitative analysis by tandem mass spectrometry Mariateresa Maldini, Paola Montoro, Sonia Piacente, Cosimo Pizza Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 29 . 6'-O-acetylscopolin C18H20O10 相似度:55.5% Chemical & Pharmaceutical Bulletin 1986 34 4012-1017 Chemical Studies on Viburnum awabuki K.KOCH MASANORI KUROYANAGI,MICHIKO SHIOTSU,TSUYOSHI EBIHARA,HIDEAKI KAWAI,AKIRA UENO and SEIGO FUKUSHIMA Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 30 . 2,4,6-trimethoxyphenol 1-O-β-D-(6'-O-galloyl)-glucopyranoside C22H26O13 相似度:55.5% Chemical & Pharmaceutical Bulletin 1982 30 2061-2067 Tannins and Related Compounds. IV. Seven New Phenol Glucoside Gallates from Quercus stenophylla MAKINO (1) GENICHIRO NONAKA,HIROAKI NISHIMURA and ITSUO NISHIOKA Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 31 . oldhamioside C23H28O13 相似度:55.5% Chinese Chemical Letters 2004 15 52-54 Oldhamioside, A New Phenolic Glucoside from Daphniphyllum oldhamii Zhi Yu SHAO, Da Yuan ZHU, Yue Wei GUO Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 32 . 2,4,6-trimethoxyphenol 1-O-β-D-(6'-O-galloyl)-glucopyranoside 相似度:55.5% China Journal of Chinese Materia Medica 2005 30 42-43 Studies on the chemical constituents I nvine stem of Bauhinia championii (I) BAI Haiyun, ZHANG Qingfeng, XIA Zenghua, LAO Aina Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 33 . 3,4-dimethoxyphenyl-1-O-β-D-apiofuranosyl (1→2)-β-D-glucopyranoside C19H29O12 相似度:55.5% Fitoterapia 2004 75 417-419 A new phenolic glycoside from Sorocea ilicifolia stem bark F. Ferrari, F. Delle Monache Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 34 . Fraxetin-7-β-D-glucopyranoside C10H8O5 相似度:55.5% Zeitschrift für Naturforschung B 2005 60b 677-682 A Phenol Glucoside, Uncommon Coumarins and Flavonoids from Pelargonium sidoides DC Tanja Gödecke, Maki Kaloga, and Herbert Kolodziej Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 35 . 3,5-dimethoxy-4-hydroxyphenol 1-O-β-D-(6'-O-galloyl)glucopyranoside C21O13H24 相似度:55.5% Phytochemistry 1987 26 1147-1152 Phenolic glucoside gallates from quercus mongolica and q. acutissima Kanji Ishimaru,Gen-Ichiro Nonaka,Itsuo Nishioka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 36 . Symcomoside A C22H26O13 相似度:55.5% Magnetic Resonance in Chmesitry 2005 43 486-488 Structure determination of bioactive galloyl derivatives by NMR spectroscopy Viqar Uddin Ahmad, Muhammad Zubair, Muhammad Athar Abbasi, Muhammad Abid Rashid, Nasir Rasool, Shamsun Nahar Khan, M. Iqbal Choudhary and Farzana Kousar Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 37 . 1,6-Di-O-syringoyl-β-D-glucopyranose C24H28O14 相似度:55.5% Journal of Asian Natural products Research 2010 12 740-744 Two new glycosides from Leonurus japonicus Jin-Ming Chang; Chien-Chang Shen; Yu-Ling Huang; Bor-Jinn Shieh; Chien-Chih Chen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 38 . digupigan A 相似度:55.5% Chinese Traditional and Herbal Drugs 2003 34 580-581 Chemical studies on root bark of Lycium chinense WEI Xiu Li; LIANG Jing Yu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 39 . isotachioside 相似度:55.5% Chinese Traditional and Herbal Drugs 2002 33 498-499 萹蓄的化学成分研究 于兆海,孙结 Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 40 . isotachioside 相似度:55.5% Chinese Pharmaceutical Journal 2003 38 12-14 Studies on the chemical constituents of Polygonum cuspidatum XIAO Kai, XUAN Li jiang, XU Ya ming, BAI Dong lu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 41 . isotachioside 相似度:55.5% Natural Product Research and Development 2004 16 496-499 GLYCOSIDES FROM THE STEMS OF PHOTINIA PARVIFOLIA ZHANG Dong-ming; LI Yuan; YU Shi-shan Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 42 . 1-(3,5-dimethoxy-4-hydroxybenzyl)-6-O-galloyl-1-O-β-D-glucopyranoside C22H26O13 相似度:55.5% Journal of Chinese Pharmaceutical Sciences 2010 19 256-259 Phenolic glucopyranosides from the Chinese mangrove plant Excoecaria agallocha L. Yong-Xin Li; Xia Yu; Shan-Jiang Yu; Ai-Ying Ma; Zhi-Wei Deng; Wen-Han Lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 43 . 6'-O-vanilloylarbutin C20H22O10 相似度:55% Journal of Asian Natural Products Research 2006 8 391-396 Antioxidant phenolic glucosides from Gentiana piasezkii Q.-X. WU, Y. LI and Y.-P. SHI Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 44 . ((3S,4S,5R,6S)-3,4,5-trihydroxy-6-(2-hydroxy-4-(2-hydroxyethyl)phenoxy)-tetrahydro-2H-pyran-2-yl)methyl 4-hydroxy-3,5-dimethoxybenzoate C23H28O12 相似度:55% Phytochemistry 2011 72 2244-2252 Terpenoids and phenethyl glucosides from Hyssopus cuspidatus (Labiatae) Megumi Furukawa, Mitsuko Makino, Emika Ohkoshi, Taketo Uchiyama, Yasuo Fujimoto Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 45 . 4-hydroxy-3-methoxyphenol 1-O-β-D-(2',6'-di-O-galloyl)glucoside C27H26O16 相似度:55% Phytochemistry 1989 28 2443-2446 Phenol glucoside gallates from Mallotus japonicus Reiko Saijo,Gen-ichiro Nonaka,Itsuo Nishioka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 46 . Rhaponticin 相似度:55% Archives of Pharmacal Research 2008 31 598-605 Lipoxygenase inhibitory constituents from rhubarb Tran Minh Ngoc, Pham Thi Hong Minh, Tran Manh Hung, Phuong Thien Thuong and IkSoo Lee, et al. Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 47 . Isorhapontin 相似度:55% Archives of Pharmacal Research 2008 31 598-605 Lipoxygenase inhibitory constituents from rhubarb Tran Minh Ngoc, Pham Thi Hong Minh, Tran Manh Hung, Phuong Thien Thuong and IkSoo Lee, et al. Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 48 . 1'-O-β-D-(3,4-dihydroxyphenyl)-ethyl-6'-O-vanilloyl-glucopyranoside 相似度:55% Journal of Shenyang Pharmaceutical University 2011 28 116-119 Isolation and identification of chemical constituents from stems of Stauntonia brachyanthera Hand. - Mazz. CHEN Chao, LI Zhen-xing, MENG Da-li, LI Ning, LI Xian Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 49 . 4-[6-O-(4-hydroxy-3,5-dimethoxybenzoyl)- β-D-glucopyranosyloxy]-3-methoxybenzoic acid C23H26O13 相似度:54.5% Chemical & Pharmaceutical Bulletin 2007 55(2) 273-279 New Glycosides from the Rhizomes of Tacca chantrieri Akihito YOKOSUKA and Yoshihiro MIMAKI Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 50 . gnetifolin E 相似度:52.6% Helvetica Chimica Acta 2008 Vol. 91 159 Stilbene Derivatives from Gnetum montanum Markgr. f. megalocarpum Markgr. Li-Qin Wang, You-Xing Zhao, Jiang Miao Hu, Ai-Qun Jia, and Jun Zhou Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 51 . 东紫苏素 A C19H28O12 相似度:52.6% Chinese Traditional and Herbal Drugs 2006 37 18-20 Chemical constituents of Elsholtzia bodinieri HU Hao-bin; LIU Jian-xin; ZHENG Xu-dong Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 52 . 1,2-dihydroxy-4-methoxybenzene 1-O-α-L-rhamnopyranosyl-(1→6)-β-D-glucopyranoside C19H28O12 相似度:52.6% CHEMISTRY & BIODIVERSITY 2011 8 1891-1900 Phenolic Compounds from the Whole Plants of Gentiana rhodantha (Gentianaceae) Min Xu, Ming Zhang, Dong Wang, Chong-Ren Yang and Ying-Jun Zhang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 53 . ligusinenoside A C21H30O12 相似度:52.3% Helvetica Chimica Acta 2007 Vol. 90 158 Chemical Constituents of Ligusticum sinensis OLIV. Jian-Ping Ma, Chang-Heng Tan, and Da-Yuan Zhu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 54 . dunalianoside C C21H22O11 相似度:52.3% Phytochemistry 2008 69 3087-3094 Caffeoyl arbutin and related compounds from the buds of Vaccinium dunalianum Ping Zhao, Takashi Tanaka, Keisuke Hirabayashi, Ying-Jun Zhang, Chong-Ren Yang, Isao Kouno Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 55 . 1-O-3′,4′-dimethoxyphenyl-(2-O-galloyl-6-O-sulfate)-β-D-glucopyranoside C21H23O15SNa 相似度:52.3% Journal of Natural Products 2008 71(5) 914-917 Phenolic Glycosides from the Stem Bark of Caryocar villosum and C. glabrum Abdulmagid Alabdul Magid, Laurence Voutquenne-Nazabadioko,Dominique Harakat, Christian Moretti, and Catherine Lavaud Structure 13C NMR 碳谱模拟图 |
2楼2012-08-22 08:58:49
杨大松
至尊木虫 (文坛精英)
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3楼2012-08-22 09:57:49
