应《网络安全法》要求，自2017年10月1日起，未进行实名认证将不得使用互联网跟帖服务。为保障您的帐号能够正常使用，请尽快对帐号进行手机号验证，感谢您的理解与支持！

24小时热门版块排行榜    

小木虫论坛-学术科研互动平台 » 化学化工区 » 催化 » 催化反应 » 磷钼酸水溶液催化纤维素转化一步法制备乙醇酸
11/1返回列表
查看: 215  |  回复: 0
只看楼主@他人 存档 新回复提醒 (忽略) 收藏    在APP中查看

xyzzz986

木虫 (著名写手)

[交流] 磷钼酸水溶液催化纤维素转化一步法制备乙醇酸

Direct Conversion of Cellulose to Glycolic Acid with a Phosphomolybdic Acid Catalyst in a Water Medium

http://pubs.acs.org/doi/abs/10.1021/cs300342k

Direct conversion of cellulose to fine chemicals has rarely been achieved. We describe here an eco-benign route for directly converting various cellulose-based biomasses to glycolic acid in a water medium and oxygen atmosphere in which heteromolybdic acids act as multifunctional catalysts to catalyze the hydrolysis of cellulose, the fragmentation of monosaccharides, and the selective oxidation of fragmentation products. With commercial α-cellulose powder as the substrate, the yield of glycolic acid reaches 49.3%. This catalytic system is also effective with raw cellulosic biomass, such as bagasse or hay, as the starting materials, giving rise to remarkable glycolic acid yields of 30%. Our heteropoly acid-based catalyst can be recovered in solid form after reaction by distilling out the products and solvent for reuse, and it exhibits consistently high performance in multiple reaction runs.
回复此楼

» 猜你喜欢
1楼2012-08-11 06:56:38
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

智能机器人

Robot (super robot)

我们都爱小木虫

找到一些相关的精华帖子，希望有用哦~

科研从小木虫开始，人人为我，我为人人
相关版块跳转 我要订阅楼主 xyzzz986 的主题更新
11/1返回列表
普通表情 龙 兔 虎 猫 高级回复(可上传附件)
信息提示
关闭
请填处理意见
关闭