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[×ÊÔ´] Review on methods to deposit catalysts on structured surfaces(TOP25)

Review on methods to deposit catalysts on structured surfaces

Val¨¦rie Meillea,  aLaboratoire de G¨¦nie des Proc¨¦d¨¦s Catalytiques, CNRS-CPE, 43 bd du 11 novembre 1918, BP 2077, 69616 Villeurbanne Cedex, France
Received 3 July 2006;  revised 17 August 2006;  accepted 18 August 2006.  Available online 9 October 2006.


Abstract

The methods used to deposit a catalyst on structured surfaces are reviewed. Physical methods such as PVD and chemical methods (sol¨Cgel, CVD, direct synthesis, etc.) are described. The coating of catalysts based on oxide, zeolite or carbon support is detailed on various surfaces such as silicon or steel microstructured reactors, cordierite monoliths or foams, fibres, tubes, etc.

Graphical abstract


Methods used to deposit metal-on-oxide catalysts, zeolite catalysts or carbon-based catalysts on structured substrates (wall-reactors) are reviewed. Wet-procedures such as suspension or sol¨Cgel as well as physical methods such as sputtering are explained and compared with some examples. A large range of substrates is concerned: silicon microreactors, ceramic monoliths, steel foams, etc.  

Keywords: Washcoating; Coating; Alumina deposition; Carbon deposition; Catalytic film; CVD; PVD; Suspension; Sol¨Cgel; Zeolite; Structured reactor; Wall-reactor; Microreactor


Article Outline

1. Introduction
2. Catalysts based on oxide supports deposited on various structures
2.1. (Pre)treatment of the substrate
2.1.1. Anodic oxidation
2.1.2. Thermal oxidation
2.1.3. Chemical treatment
2.2. Coating methods based on a liquid phase
2.2.1. Suspension
2.2.2. Sol¨Cgel deposition
2.2.3. Hybrid method between suspension and sol¨Cgel
2.2.4. Deposition on structured objects from suspension, sol¨Cgel or hybrid methods
2.2.5. Electrophoretic deposition (EPD)
2.2.6. Electrochemical deposition and electroless plating
2.2.7. Impregnation
2.3. Other ways
2.3.1. CVD
2.3.2. Physical vapor deposition (PVD)
2.3.2.1. Cathodic sputtering
2.3.2.2. Electron-beam evaporation
2.3.2.3. Pulsed laser deposition (PLD)
2.3.3. Flame assisted vapor deposition (FAVD), flame spray deposition (FSD) and powder plasma spraying
2.4. Comparison of the results obtained by different methods¡ªwhich method for which application
3. Synthesis of zeolites on various structures
4. Catalysts based on carbon support deposited on various structures
4.1. Deposition on ceramic surface
4.2. Deposition on metallic surfaces
5. Conclusion
References

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http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TF5-4M2WP1K-1-7C&_cdi=5217&_user=5774141&_orig=search&_coverDate=11%2F23%2F2006&_sk=996849999&view=c&wchp=dGLbVlb-zSkzV&md5=c417c6ebb4decf3e187c8732af09b7fc&ie=/sdarticle.pdf

[ Last edited by daiqiguang on 2007-5-8 at 20:27 ]
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