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Accession number: 20120914807197 Title: Effect of fluorine content on the electrochemical properties of pvdf-derived carbons for lithium ion battery Authors: Shi, Lu1 ; Miao, Chaolin1 ; Chen, Gairong1 ; Xu, Bin2 ; Chen, Shi3 Author affiliation: 1 College of Chemistry and Chemical Engineering, Xinxiang University, Henan Xinxiang 453000, China 2 Research Institute of Chemical Defense, Beijing 100191, China 3 Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China Corresponding author: Xu, B. (xubin@bit.edu.cn) Source title: Advanced Materials Research Abbreviated source title: Adv. Mater. Res. Volume: 463-464 Monograph title: Advanced Materials Research II Issue date: 2012 Publication year: 2012 Pages: 730-733 Language: English ISSN: 10226680 ISBN-13: 9783037853634 Document type: Conference article (CA) Conference name: 2012 2nd International Conference on Advanced Material Research, ICAMR 2012 Conference date: January 7, 2012 - January 8, 2012 Conference location: Chengdu, China Conference code: 88640 Sponsor: Singapore Institute of Electronics (SIE); Science and Engineering Institute (SCIEI) Publisher: Trans Tech Publications, P.O. Box 1254, Clausthal-Zellerfeld, D-38670, Germany Abstract: The carbon materials prepared by PVDF carbonization at different temperatures have similar BET surface area and pores volume. The content of fluorine in the carbons decreased with the carbonization temperature from 1.46% (atm %) at 600¡ãC to 0.18 %(atm %) at 1000¡ãC. The first cycle specific capacity and the initial coulombic efficiency decreases with the decrease of fluorine content in the samples. The first cycle discharge capacity decreased from 982 mAh/g at 600¡ãC to 752 mAh/g at 1000¡ãC and the initial coulombic efficiency decreased from 31.8% at 600¡ãC to 24% at 1000¡ãC. It is believed that fluorine contained in the carbon materials has a positive effect to improve the electrochemical properties as anode materials for Li-ion batteries. © (2012) Trans Tech Publications. Number of references: 10 Main heading: Fluorine Controlled terms: Anodes - Carbonization - Electrochemical properties - Internet protocols - Lithium batteries Uncontrolled terms: Anode material - BET surface area - Carbon material - Carbonization temperatures - Coulombic efficiency - Discharge capacities - First cycle - Fluorine content - Initial Coulombic efficiency - Li-ion batteries - Lithium ion battery - Positive effects - Specific capacities Classification code: 445.1 Water Treatment Techniques - 549.1 Alkali Metals - 723 Computer Software, Data Handling and Applications - 801.4.1 Electrochemistry - 802.1 Chemical Plants and Equipment - 804 Chemical Products Generally DOI: 10.4028/www.scientific.net/AMR.463-464.730 Database: Compendex |
2Â¥2012-05-28 17:43:29
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3Â¥2012-05-28 18:06:27
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