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Èç¹ûдµÄÌ«²î£¬Çë°ïæ·­Òëһϡ£¡£Carboxymethyl chitosan microspheres were prepared as raw product using chitosan as original material, glutaraldehyde as the cross-linking agent,and chloroacetic acid as the carboxymethylation substance.Then modified by molecular imprinting technology using Ni2+ ion as template.for use in the adsorbtion of Ni2+.The condition of imprinting modification and absotbtion were studied.The results showed that the best modification was got when Ni2+ concentration was 5g/L,glutaraldehyde dosage was 20mL and elutingtime is 7h and the maximum adsorbtion for Ni2+ occured at pH=8, adsorbentdosage was 60 mg,adsorption time was 80 min and adsorption temperature was 25¡æ.Compared absorbtions of modified carboxymethyl chitosan microspheres and chitosan to Ni2+ in wastewater which were 62.45% and 47.97%,indicating that the absorbtion property of the former is better.

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Mally89: ½ð±Ò+1, ¸ÐлӦÖú£¡~»¶Ó­³£À´£¡~ºðºð£¡~\(^o^)/~ 2012-05-18 17:29:26
¶«ÆÂС°×: ½ð±Ò+10, ·­ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, ÆÀ¼ÛÍíÁË¡£¡£·Ç³£¸ÐлÄãµÄ°ïÖú£¡£¡ 2012-05-20 23:00:19
Carboxymethyl chitosan microspheres were prepared by using chitosan as the original material, glutaraldehyde as the cross-linking agent, and chloroacetic acid as the carboxymethylation substance. Then the  microspheres were furtherly modified by molecular imprinting technology using Ni2+ ion as template, to obtain the imprinted modified carboxymethyl chitosan microspheres. The influence of nickel concentration, the glutaraldehyde dosage, and elution time on the imprinted cross-linked modification was investigated. The results showed that the best modified conditions were: 5g/L Ni2+ concentration, 20mL glutaraldehyde and 7h elution time.  The best adsorption conditions£¬where the maximum adsorption of nickel by modified carboxymethyl chitosan microspheres occurred£¬were that£ºpH=8, adsorbent dosage was 60 mg, adsorption time was 80 min and adsorption temperature was 25¡æ. We also compared the adsorption effects between self - made imprinting modified carboxymethyl chitosan microspheres and chitosan by using Ni2+-containing wastewater, and the adsorption rates were 62.45% and 47.97% respectively, indicating that the adsorption properties of modified carboxymethyl chitosan microspheres have been greatly improved.
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