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±¾ÂÛÎIJÉÓú˴ʲÕñ¹âÆ×£¨NMR£©Ñо¿ÁËZSM-22/ZSM-23¹²½á¾§·Ö×Óɸ¸ºÔعó½ðÊôÖÆ±¸µÄ´ß»¯¼ÁµÄ¼ÓÇâÒì¹¹·´Ó¦ÐÔÄÜ£¬Í¨¹ý200SNÍÑÀ¯ÓÍ¡¢650SN¿·È©¾«ÖÆÓͺͼÓÇâÁÑ»¯Î²ÓÍÈýÖÖÔÁÏÓͼÓÇâÒì¹¹·´Ó¦Ç°ºóÓÍÆ·µÄ½á¹¹ÌØÕ÷ºÍ½á¹¹²ÎÊý±ä»¯ÓëÇãµã¡¢Õ³¶ÈÖ¸Êýºê¹ÛÐÔÖÊÏà¹ØÁª¿ÉÖª£º¼ÓÇâÒì¹¹·´Ó¦ºó£¬»ù´¡ÓͲúÆ·µÄÖ§»¯¶È¶¼Óв»Í¬³Ì¶ÈµÄÔö´ó£¬Õý¹¹ÍéÌþº¬Á¿½µµÍ£¬Òì¹¹ÍéÌþº¬Á¿Ôö¼Ó£¬»ù´¡Ó͵ÄÇãµãºÍÕ³¶ÈÖ¸ÊýÒ²ËæÖ®½µµÍ£¬µ«ÊÇ»ù´¡ÓͲúÆ·µÄƽ¾ùÁ´³¤±ä»¯½ÏÉÙ£¬±íÃ÷ÁËZSM-22/ZSM-23¹²½á¾§·Ö×Óɸ¸ºÔعó½ðÊôÖÆ±¸µÄ´ß»¯¼ÁÓнϺõļÓÇâÒì¹¹ÐÔÄÜ¡£ÓëPt/ZSM-22ºÍPt/ZSM-23´ß»¯¼ÁÏà±È½Ï£¬ÔÚÈõËáÐÔµÄPt/ZSM-22/ZSM-23´ß»¯¼ÁÉÏ650SN¿·È©¾«ÖÆÓ;¼ÓÇâÒì¹¹·´Ó¦µÃµ½µÄ²úÆ·ÖÐÒì¹¹Ìþº¬Á¿½Ï¶à£¬Æ½¾ùÁ´³¤½Ï´ó£¬Pt/ZSM-22/ZSM-23´ß»¯¼Á±íÏÖ³öÁ˽ϺõļÓÇâÒì¹¹ÐÔÄÜ¡£ The hydroisomerization performance of ZSM-22/ZSM-23 which loaded noble metal was studied by NMR. According to the variety of strcture characters and structure index, and associated with macroscopic properties such as pour point and viscosity index for 200SN, 650SN, hydrocracking tail oil and their isomerization products, it shown the branch degree of lube base oil products increased in varying degrees, normal paraffin content decreased, and the isoparaffin content increased after hydroisomerization reaction, so the pour point and viscosity index of base oil also decreased, but the average chain length changed little. Compared with the Pt/ZSM-22 and Pt/ZSM-23 catalyst, 650SN furfural refined oil after hydroisomerization on Pt/ZSM-22/ZSM-23 catalyst which had weaker acidity, the products had more isoparaffin, and longer average chain length, which indicated that Pt/ZSM-22/ZSM-23 has better hydroisomerization performance. |
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ÖÁ×ðľ³æ (Ö°Òµ×÷¼Ò)
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sltmac: ½ð±Ò+1 2012-05-03 08:53:49
ankang276: ½ð±Ò+30, ·ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú 2012-05-03 13:36:33
sltmac: ½ð±Ò+1 2012-05-03 08:53:49
ankang276: ½ð±Ò+30, ·ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú 2012-05-03 13:36:33
| The hydroisomerization performance of the catalyst of ZSM-22/ZSM-23 cocrystallization molecules loaded onto noble metal was studied through nuclear magentic resonance spectroscopy (NMR). By associating the change of strcture characters and structure index of oils before and after hydroisomerization reactions with macroscopic properties including pour point and viscosity index of 200SN, 650SN, hydrocracking tail oil and their corresponding isomerization products, it can be known that the branch degree of lube base oil products increased to various extents, the content of normal paraffin decreased, and the content of isoparaffin increased after hydroisomerization reaction, and thus the pour point and viscosity index of base oil also decreased while the average chain length changed little. Compared with on Pt/ZSM-22 and Pt/ZSM-23 catalysts, the products of 650SN furfural refined oil after hydroisomerization on the Pt/ZSM-22/ZSM-23 catalyst with weak acidity had more isoparaffin, and longer average chain length. It indicated better hydroisomerization performance of Pt/ZSM-22/ZSM-23 than that of Pt/ZSM-22 and Pt/ZSM-23 catalysts. |
2Â¥2012-05-03 08:48:51









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