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北京石油化工学院2026年研究生招生接收调剂公告
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jjxiang

捐助贵宾 (著名写手)

[求助] Suzuki反应在高分子研究中的进展

本人才开始研究高分子,急需Suzuki反应在高分子研究中的进展方面的文章!!!金币不是问题,也欢迎和大家交流下这个方向!!本人才开始,什么都不懂· ···
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Suzuki Reaction

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下一步,做自己!!
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shouwen

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jjxiang: 金币+5 2012-05-01 22:16:11
建议先看看这篇:J. POLYM. SCI. PART A: POLYM. CHEM. 39 1533–1556.
The Tenth Anniversary of Suzuki Polycondensation (SPC)
This article describes the successful transfer of the Suzuki cross-coupling (SCC) reaction to polymer synthesis, one of the major developments within the last decade of polymer synthesis. The polymers prepared by Suzuki polycondensation (SPC) and its Ni-catalyzed reductive counterpart are soluble and processable poly(arylene)s that, because of their rigid and conjugated backbones, are of interest for the materials sciences. Achievable molar masses easily compete with those of traditional polyesters and polyamides. This article also provides insight into some synthetic problems associated with the transfer of SCC from low molar mass organic chemistry to high molar mass polymer chemistry by addressing issues such as monomer purity,stoichiometric balance, achievable molar masses, and defects in the polymer structure. Although the emphasis of this article is synthetic and structural issues, some potential applications of the polyarylenes obtained are briefly mentioned. Together with the enormous developments in the areas of metallocene, ring-opening metathesis, and acyclic diene metathesis polymerization, the success of SPC impressingly underlines the increasing importance of transition-metal-catalyzed CC-bondforming reactions in polymer synthesis.
4楼2012-05-01 22:08:07
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suding

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jjxiang: 金币+5 2012-05-01 13:26:13
wgs8136: 金币+1 2012-05-01 15:26:42
Recent applications of the Suzuki– Miyaura cross-coupling reaction in organic synthesis, ~~~~~~~~~~~~~
人在江湖,以仁為人,以韌為事,精誠所至,金石為開。
2楼2012-05-01 11:44:49
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Actor2006

至尊木虫 (知名作家)

引用回帖:
4楼: Originally posted by shouwen at 2012-05-01 22:08:07:
建议先看看这篇:J. POLYM. SCI. PART A: POLYM. CHEM. 39 1533–1556.
The Tenth Anniversary of Suzuki Polycondensation (SPC)
This article describes the successful transfer of the Suzuki cross-coupli ...

学习,谢谢!
nanoeverest
5楼2012-05-02 08:58:28
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chengcj.2008

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4楼: Originally posted by shouwen at 2012-05-01 22:08:07:
建议先看看这篇:J. POLYM. SCI. PART A: POLYM. CHEM. 39 1533–1556.
The Tenth Anniversary of Suzuki Polycondensation (SPC)
This article describes the successful transfer of the Suzuki cross-coupli ...

学习了, 感谢分享.
6楼2012-05-02 10:07:01
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