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| The tie line joining the composition of the pure solid and the saturated liquid in equilibrium with it is the locus of all intermediate compositions corresponding to varying amounts of solid and liquid phase. This includes the composition of the liquid phase and crystals wet with mother liquor. A straight line drawn through a pair of points representing such compositions on a phase diagram is a segment of the tie line, and therefore passes through the composition of the pure solid. The lines drawn through several such pairs of composition, each corresponding to a different original mixture, have a common intersection at the composition of the pure solid phase. The composition of the common intersection is in agreement with direct analysis obtained by crystallization. |
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