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| Aliquots of saturated sodium 3-nitrobenzenesulphonate and sodium 4-nitrobenzenesulphonate solutions are transferred through a coarse filter into a tarred volumetric flask. The concentration of 3- or/and sodium 4-nitrobenzenesulphonate in water is determined using a Shimadzu-6A high-performance liquid phase chromatograph (HPLC). The Diamonsil C18 (150 mm¡Á4.6mm) chromatographic column is used. The mobile phase consists of three eluents which are water, Na2SO4 and H3PO4. The uncertainty of the measurement is less than 0.001 g of sodium 3-nitrobenzenesulphonate or sodium 4-nitrobenzenesulphonate per 100 g of water. The densities (¦Ñ) of the equilibrium liquid phase are measured using a pycnometer (11-FY) with an uncertainty of 0.0002 gcm-3. The densities of the equilibrated solution were measured with a gravity bottle method with a precision of (0.0002 g and used for mass fraction calculation of liquid components. The specific gravity bottle method with correction of the air floating force was used. The density of dry air at 293.15 K and normal atmospheric pressure. Each analysis is repeated three times, and the average value of the three measurements is considered as the final value of the analysis.18-19 |
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- Ó¦Öú: 13 (СѧÉú)
- ¹ó±ö: 0.566
- ½ð±Ò: 17176.4
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- ×¢²á: 2011-03-19
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sltmac: ½ð±Ò+1 2012-04-22 08:30:20
-ÐùÓ°øS: ½ð±Ò+10, ·ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2012-04-22 09:24:43
sltmac: ½ð±Ò+1 2012-04-22 08:30:20
-ÐùÓ°øS: ½ð±Ò+10, ·ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2012-04-22 09:24:43
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