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ÏÂÃæÊÇÎÒµÄÕªÒªºÍÎÒдµÄ·Ò룬¸÷λ°ïæÐ޸ģ¬ÍêÉÆÏ£¬Ð»Ð»¡£ ½üÄêÀ´£¬ÒÔCeO2Ϊ»ùÖʵÄÏ¡ÍÁ·¢¹â²ÄÁϾßÓÐÁ¼ºÃµÄ¹âѧÐÔÄÜ£¬ÆäÖÆ±¸¼¼ÊõµÄ·¢Õ¹¡¢Ó«¹âÐÔÄÜÓÅ»¯ºÍ¹¦ÄÜÆ÷¼þµÄÓ¦ÓÃÒѾ³ÉΪÈËÃÇÑо¿µÄÈȵ㡣¶øÏ¡ÍÁ²ôÔÓµÄCeO2 ¾ßÓÐÌØÊâµÄ¹âѧÐÔÄÜ£¬²¢¹ã·ºÓ¦ÓÃÓÚ·¢¹â²ÄÁÏ[1]¡¢´ß»¯¼Á[2]¡¢×ÏÍâÏßÎüÊÕ²ÄÁÏ[3]¡¢»¯Ñ§»úеÅ×¹â²ÄÁÏ[4]¡¢µç×ÓÌÕ´É[5]¡¢¹ÌÌåÑõ»¯Îïµç³Ø²ÄÁÏ[6]µÈÁìÓò¡£±¾ÎIJÉÓÃË®ÈÈ·¨ÖƱ¸ÁËCeO2:Eu3+ºìɫӫ¹â·Û, ²¢Í¨¹ýXÉäÏß·ÛÄ©ÑÜÉä(XRD) ¡¢¸ß·Ö±æÍ¸Éäµç¾µ£¨HRTEM£©¡¢É¨Ãèµç×ÓÏÔ΢¾µ(SEM)¡¢×ÏÍâÂþ·´Éä¹âÆ×£¨UV-vis£©¡¢ ºìÍâ¹âÆ×ÒÇ(IR)ºÍÓ«¹â¹âÆ×(FL)µÈ¼¼Êõ±íÕ÷ÁËÑùÆ·£¬²¢Ì½ÌÖÁËÈÜÒºµÄpH¡¢·´Ó¦Ê±¼ä¡¢·´Ó¦Î¶ȣ¬Eu3+²ôÔÓŨ¶È£¬×ÆÉÕʱ¼ä£¬×ÆÉÕζȵȶԲúÆ·Ó«¹âÐÔÄܵÄÓ°Ïì¡£²âÊÔ½á¹û±íÃ÷£ºCeO2:Eu3+ÑùÆ·¾ßÓÐÁ¼ºÃµÄ½á¾§¶È£¬ÊôÓÚÁ¢·½Ó©Ê¯½á¹¹µÄµ¥¾§·ÛÄ©£¬Æä¾§Á£³ß´çÔÚ12-50 nmÄÚ¡£Ó«¹â½á¹û±íÃ÷£ºCeO2?Eu3+ÄÉÃ×¾§ÔÚ593¡¢612¡¢632 nm ´¦¾ßÓнÏÇ¿µÄ·¢Éä·å(ºì¹â)£¬¶øÇҽϸߵÄÍË»ðζÈÓÐÀûÓÚÌá¸ßÑùÆ·µÄ¾§»¯¶ÈºÍÓ«¹âÇ¿¶È¡£ In recent years, the rare earth luminescence materials which made from CeO2 have good optical performance. The development of preparation technology, optimization of fluorescence performance and application of functional devices of rare earth luminescence materials have become a research hot spot. And the CeO2 which doped with rare earth has special optical properties, and widely used in the field of luminescence materials, catalyst, ultraviolet ray absorption materials, chemical mechanical polishing materials, electronic ceramic and solid oxide battery materials and so on. CeO2:Eu3+ red phosphors were successfully synthesized by hydrothermal method .The samples were characterized by XRD, HRTEM, SEM, UV-Vis, IR and FL technologies. And it also investigated the effects of pH values of solution, reaction time, reaction temperature£¬dosage concentration of Eu3+ , firing time and firing temperature to the performance of product fluorescence. The results indicated that the sample CeO2:Eu3+ was well crystallized with a good crystallinity. It was monocrystal powder in cube fluorite and the size of grain was around 12~50 nm. The fluorescence measurements show that the CeO2:Eu3+ nano-crystals possess good emission intensities at 593, 612 and 632nm respectively. And the crystallinity and fluorescence intensity of the sample were improved by increasing annealing temperature. |
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money4u
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 26
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 12804.8
- ºì»¨: 1
- Ìû×Ó: 1773
- ÔÚÏß: 107.6Сʱ
- ³æºÅ: 425515
- ×¢²á: 2007-07-27
- ÐÔ±ð: GG
- רҵ: ÎïÀíѧI
¡¾´ð°¸¡¿Ó¦Öú»ØÌû
¡ï ¡ï ¡ï ¡ï ¡ï
Á¬__Éú: ½ð±Ò+3, ·ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú, лл 2012-04-11 11:30:12
sltmac: ½ð±Ò+2 2012-04-26 10:46:03
Á¬__Éú: ½ð±Ò+3, ·ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú, лл 2012-04-11 11:30:12
sltmac: ½ð±Ò+2 2012-04-26 10:46:03
| As rare-earth luminescence materials based on CeO2 have showed very good optical performance, the research on the development of preparation technology, optimization of fluorescence performance and application of functional devices involving in the materials have been being a hot spot in recent years. |

2Â¥2012-04-10 18:12:17
money4u
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 26
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 12804.8
- ºì»¨: 1
- Ìû×Ó: 1773
- ÔÚÏß: 107.6Сʱ
- ³æºÅ: 425515
- ×¢²á: 2007-07-27
- ÐÔ±ð: GG
- רҵ: ÎïÀíѧI

3Â¥2012-04-10 22:46:03
money4u
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 26
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 12804.8
- ºì»¨: 1
- Ìû×Ó: 1773
- ÔÚÏß: 107.6Сʱ
- ³æºÅ: 425515
- ×¢²á: 2007-07-27
- ÐÔ±ð: GG
- רҵ: ÎïÀíѧI
¡¾´ð°¸¡¿Ó¦Öú»ØÌû
| The CeO2:Eu3+ red phosphors, which is successfully synthesized by hydrothermal method, has been characterized by means of XRD, HRTEM, SEM, UV-Vis, IR and FL technologies. The influences of the process conditions including pH values of the solution, reacting time, reacting temperature, concentration of Eu3+ , firing time and firing temperature on the fluorescence performance are also investigated. |

4Â¥2012-04-10 23:00:35
money4u
ÖÁ×ðľ³æ (ÖøÃûдÊÖ)
- ·ÒëEPI: 26
- Ó¦Öú: 0 (Ó×¶ùÔ°)
- ½ð±Ò: 12804.8
- ºì»¨: 1
- Ìû×Ó: 1773
- ÔÚÏß: 107.6Сʱ
- ³æºÅ: 425515
- ×¢²á: 2007-07-27
- ÐÔ±ð: GG
- רҵ: ÎïÀíѧI
¡¾´ð°¸¡¿Ó¦Öú»ØÌû
¡ï ¡ï
Mally89: ½ð±Ò+2, ¸ÐлӦÖú£¡~»¶Ó³£À´£¡~ºÃÔË£¡~\(^o^)/~ 2012-04-14 13:04:43
Mally89: ½ð±Ò+2, ¸ÐлӦÖú£¡~»¶Ó³£À´£¡~ºÃÔË£¡~\(^o^)/~ 2012-04-14 13:04:43
| The testing results indicate that the sample CeO2:Eu3+ is well crystallized with a good crystallinity, the monocrystal powders are of cubic fluorite structure, and size of the grains are around 12nm to 50 nm. The fluorescence measurements show that the CeO2:Eu3+ nano-crystals possess good emission intensities at 593nm, 612nm and 632nm respectively, and higher annealing temperature is good for the crystallinity and fluorescence intensity of the sample. |

5Â¥2012-04-10 23:20:48














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