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Abstract White and fluffy Al-doped zinc oxide powders
were fabricated using ZnO and Al(C3H7O)3 powders by a
solid statemethod.The effects of Al doping on microstructure,
electrical and optical properties were systematically studied.
XRDand Raman results showthat the Al-doped powders have
a pure hexagonal wurtzite structure. The resistivity of ZnO
could be decreased from 108 to 102 X cm with the Al doped
concentration of 3 at.%. Meanwhile, the obtained powders
exhibited high diffuse reflectance in visible region, intense
UV emission without deep level emission and good environmental
stability. Results reveal that the optical property of the
powders has an intimate relationship with the electrical
property. The decline of the diffuse reflectance at visible
wavelengths and the strong IR absorption were due to the
increase of the free electron concentration. Al doping leads to
quenching of defect related visible band emission, and we
surmise that the defect centers are mainly related to oxygen
vacancies (VO) and zinc vacancies (VZn). Al doping mechanism
was also tentatively explored.

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