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xujuliang

铜虫 (小有名气)

[求助] thin solid films 审稿回复求助

大牛们,小弟投了一篇Thin Solid Films,已经修改两次了,最近刚刚又回来让修改。原文中我用EIS测试了MnO2的性能,并进行了拟合。在拟合过程中选用了一个等效电路,而且拟合的结果非常符合实际测量的结果。审稿人的问题是:How was the equivalent circuit obtained?
我把这两次的问答都贴上来,想求教一下大牛们改怎么回答。

My First response:  The equivalent circuit was obtained according to the physical structure of the whole electrode. Besides, the fitted line was well consisted with the real data obtained by experiments. So we chose this equivalent circuit.

Reviewer‘s assessment:  I guess this is okay, but the authors did not really answer my question.  I realize they fit to the circuit in Figure 15; I was looking for justification.  

My Second response:  The equivalent circuit was obtained from ref. 40 (C.J. Xu, H.D. Du, B.H. Li, F.Y. Kang, Y.Q. Zeng, J. Electrochem. Soc. 156 (2009) A73.). The reference was added in the manuscript.  (Page 11, line 21)

Reviewer’s assessment:  It is good to add the reference, but there is still no justification for the circuit.
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hls85915

荣誉版主 (文坛精英)

科研工具版——沙漠之胡

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【答案】应助回帖

感谢参与,应助指数 +1
My First response:  The equivalent circuit was obtained according to the physical structure of the whole electrode. Besides, the fitted line was well consisted with the real data obtained by experiments. So we chose this equivalent circuit.

Reviewer‘s assessment:  I guess this is okay, but the authors did not really answer my question.  I realize they fit to the circuit in Figure 15; I was looking for justification.  

这个是要求你从原理上阐述,为什么实验和模型相符合

My Second response:  The equivalent circuit was obtained from ref. 40 (C.J. Xu, H.D. Du, B.H. Li, F.Y. Kang, Y.Q. Zeng, J. Electrochem. Soc. 156 (2009) A73.). The reference was added in the manuscript.  (Page 11, line 21)

Reviewer’s assessment:  It is good to add the reference, but there is still no justification for the circuit.

你把equivalent circuit 原理详细说明下
哈哈
2楼2012-03-28 09:31:41
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Love_Matrix

木虫 (正式写手)

【答案】应助回帖

感谢参与,应助指数 +1
所以说不能只参考就行,拟合是有随意性的,残差只是相对的,拟合的再好不一定模型就正确,
3楼2012-04-03 20:39:51
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qiqiqiqi

至尊木虫 (知名作家)

小木虫发型设计师

【答案】应助回帖

感谢参与,应助指数 +1
同意楼上两位说法 另审稿人给出的文献要引用上
http://edu.emuch.net/attachment/b0/a6/664055_1294967861_445.gif
4楼2012-04-05 22:02:01
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xujuliang

铜虫 (小有名气)

引用回帖:
2楼: Originally posted by hls85915 at 2012-03-28 09:31:41:
My First response:  The equivalent circuit was obtained according to the physical structure of the whole electrode. Besides, the fitted line was well consisted with the real data obtained by experi ...

我在文章中已经明确说了equivalent circuit中各个元件的物理意义
5楼2012-04-06 11:09:06
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