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IL-USA-DLLME method used to simultaneously extract and determine four phenylurea herbicides in water samples£¬Current Analytical Chemistry£¬2011
7 ( 4): 357-364

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FN Thomson Reuters Web of Knowledge
VR 1.0
PT  J
AU  Wang, SL
Liu, CY
Liu, FM
Ren, LP
AF  Wang, Suli
Liu, Congyun
Liu, Fengmao
Ren, Liping
TI  IL-USA-DLLME Method to Simultaneously Extract and Determine Four Phenylurea Herbicides in Water Samples
SO  CURRENT ANALYTICAL CHEMISTRY
LA  English
DT  Article
DE  IL-USA-DLLME; Phenylurea herbicides; Water samples; HPLC
ID  LIQUID-LIQUID MICROEXTRACTION; ULTRASOUND-ASSISTED EMULSIFICATION; ATOMIC-ABSORPTION-SPECTROMETRY; POLYCYCLIC AROMATIC-HYDROCARBONS; CHROMATOGRAPHY-MASS SPECTROMETRY; SOLID-PHASE MICROEXTRACTION; GAS-CHROMATOGRAPHY; ORGANOPHOSPHORUS PESTICIDES; FLAME RETARDANTS; SENSITIVE METHOD
AB  An ionic-liquid ultrasound-assisted dispersive liquid-liquid microextraction method (IL-USA-DLLME) was introduced to determine four phenylurea herbicides (i.e., isoproturon, monolinuron, linuron, and diuron) in water samples with high performance liquid chromatography (HPLC). The ionic liquid of 1-hexyl-3-methylimidazolium hexafluorophosphate [HMIMPF6] was dispersed into the aqueous sample solution in fine droplets by ultrasound and was used as the extraction solvent; the phenylurea herbicides were concentrated into the ionic liquid phase. The extraction conditions, such as the volume of the extraction solvent, sonication and centrifugation time, ionic strength, and the emulsification-extraction temperature, were optimized. Under the optimized conditions, the linear correlation coefficient ranged from 0.9954 to 0.9969 for concentration levels of 2-100 mu gL(-1). The good recovery (68-100%) of target analytes was obtained from the water samples. The relative standard deviations (RSDs, n=6) ranged from 2.3-9.5%, and the limits of detection (LODs) for the herbicides were between 0.10 mu gL(-1) and 0.24 mu gL(-1). The applicability of the proposed method was evaluated by the extraction and determination of phenylurea herbicides from several natural water samples.
C1  [Wang, Suli; Liu, Congyun; Liu, Fengmao; Ren, Liping] China Agr Univ, Beijing 100193, Peoples R China.
[Wang, Suli] Hebei North Univ, Zhangjiakou 075131, Peoples R China.
RP  Liu, FM (reprint author), China Agr Univ, Beijing 100193, Peoples R China
EM  lfm2000@cau.edu.cn
FU  40th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry; Natural Science Foundation of Hebei Province[B2011405007]
FX  The authors acknowledge the financial support from the 40th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry and the Natural Science Foundation of Hebei Province (No. B2011405007).
NR  34
TC  0
Z9  0
PU  BENTHAM SCIENCE PUBL LTD
PI  SHARJAH
PA  EXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATES
SN  1573-4110
J9  CURR ANAL CHEM
JI  Curr. Anal. Chem.
PD  OCT
PY  2011
VL  7
IS  4
BP  357
EP  364
PG  8
WC  Chemistry, Analytical
SC  Chemistry
GA  893KJ
UT  WOS:000300354500011
ER  

--------------------------------------------------------------------------------
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IL-USA-DLLME Method to Simultaneously Extract and Determine Four Phenylurea Herbicides in Water Samples  
×÷Õß: Wang, SL (Wang, Suli)1,2; Liu, CY (Liu, Congyun)1; Liu, FM (Liu, Fengmao)1; Ren, LP (Ren, Liping)1  
À´Ô´³ö°æÎï: CURRENT ANALYTICAL CHEMISTRY  ¾í: 7   ÆÚ: 4   Ò³: 357-364   ³ö°æÄê: OCT 2011  
±»ÒýƵ´Î: 0 (À´×Ô Web of Science)  
ÒýÓõIJο¼ÎÄÏ×: 34 [ ²é¿´ Related Records ]     ÒýÖ¤¹ØÏµÍ¼      
ÕªÒª: An ionic-liquid ultrasound-assisted dispersive liquid-liquid microextraction method (IL-USA-DLLME) was introduced to determine four phenylurea herbicides (i.e., isoproturon, monolinuron, linuron, and diuron) in water samples with high performance liquid chromatography (HPLC). The ionic liquid of 1-hexyl-3-methylimidazolium hexafluorophosphate [HMIMPF6] was dispersed into the aqueous sample solution in fine droplets by ultrasound and was used as the extraction solvent; the phenylurea herbicides were concentrated into the ionic liquid phase. The extraction conditions, such as the volume of the extraction solvent, sonication and centrifugation time, ionic strength, and the emulsification-extraction temperature, were optimized. Under the optimized conditions, the linear correlation coefficient ranged from 0.9954 to 0.9969 for concentration levels of 2-100 mu gL(-1). The good recovery (68-100%) of target analytes was obtained from the water samples. The relative standard deviations (RSDs, n=6) ranged from 2.3-9.5%, and the limits of detection (LODs) for the herbicides were between 0.10 mu gL(-1) and 0.24 mu gL(-1). The applicability of the proposed method was evaluated by the extraction and determination of phenylurea herbicides from several natural water samples.  
Èë²ØºÅ: WOS:000300354500011  
ÎÄÏ×ÀàÐÍ: Article  
ÓïÖÖ: English  
×÷Õ߹ؼü´Ê: IL-USA-DLLME; Phenylurea herbicides; Water samples; HPLC  
KeyWords Plus: LIQUID-LIQUID MICROEXTRACTION; ULTRASOUND-ASSISTED EMULSIFICATION; ATOMIC-ABSORPTION-SPECTROMETRY; POLYCYCLIC AROMATIC-HYDROCARBONS; CHROMATOGRAPHY-MASS SPECTROMETRY; SOLID-PHASE MICROEXTRACTION; GAS-CHROMATOGRAPHY; ORGANOPHOSPHORUS PESTICIDES; FLAME RETARDANTS; SENSITIVE METHOD  
ͨѶ×÷ÕßµØÖ·: Liu, FM (ͨѶ×÷Õß),China Agr Univ, Beijing 100193, Peoples R China  
µØÖ·:
1. China Agr Univ, Beijing 100193, Peoples R China
2. Hebei North Univ, Zhangjiakou 075131, Peoples R China  
µç×ÓÓʼþµØÖ·: lfm2000@cau.edu.cn  
»ù½ð×ÊÖúÖÂл:
»ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ
40th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry   
Natural Science Foundation of Hebei Province  B2011405007  

[ÏÔʾ»ù½ð×ÊÖúÐÅÏ¢][Òþ²Ø»ù½ð×ÊÖúÐÅÏ¢]   

The authors acknowledge the financial support from the 40th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry and the Natural Science Foundation of Hebei Province (No. B2011405007).

³ö°æÉÌ: BENTHAM SCIENCE PUBL LTD, EXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATES  
Web of Science ·ÖÀà: Chemistry, Analytical  
ѧ¿ÆÀà±ð: Chemistry  
IDS ºÅ: 893KJ  
ISSN: 1573-4110
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