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Brinker发表在MRS上的一篇很好的综述
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这是一篇sol-gel的很好的综述性文章,看到有人对Brinker很感兴趣,和大家分享一下,他的那本sol-gel的书如果谁有,希望也能发给我一份,先谢过了!! [ Last edited by dgf2008 on 2008-10-13 at 19:34 ] |
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★★★ 三星级,支持鼓励
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Abstract The following article is an edited transcript based on the MRS Medalist presentation given by C. Jeffrey Brinker (Sandia National Laboratories and the University of New Mexico) on December 3, 2003, at the Materials Research Society Fall Meeting in Boston. Brinker received the Medal for “his pioneering application of principles of sol-gel chemistry to the self-assembly of functional nanoscale materials.” Nature combines hard and soft materials, often in hierarchical architectures, to obtain synergistic, optimized properties with proven, complex functionalities. Emulating natural designs in robust engineering materials using efficient processing approaches represents a fundamental challenge to materials chemists. This presentation reviews progress on understanding so-called evaporation-induced silica/surfactant self-assembly (EISA) as a simple, general means of preparing porous thin-film nanostructures. Such porous materials are of interest for membranes, low-dielectric-constant (low-k) insulators, and even ‘”nano-valves” that open and close in response to an external stimulus. EISA can also be used to simultaneously organize hydrophilic and hydrophobic precursors into hybrid nanocomposites that are optically or chemically polymerizable, patternable, or adjustable. Keywords: azobenzene, functional materials, nanocomposites, nanocrystals, nanostructures, self-assembly. |
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