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Shape-Memory Polymers and Multifunctional Composites
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Editors: Jinsong Leng (Àä¾¢ËÉ), Shanyi Du (¶ÅÉÆÒå)
Format: PDF£»File Size: 8.08MB£»Page: 386
Publisher: CRC Press
Publication Date: 2010-05-25
ISBN-13: 978-1-4200-9020-8
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Description:
Admired for their extraordinary stimuli-sensitive behavior and shape-changing capabilities, shape-memory polymers (SMPs) and multifunctional composites are among the most important smart materials. They continue to be widely applied in many diverse fields to create things such as self-deployable spacecraft structures, morphing structures, SMP foams, smart textiles, and intelligent medical devices.
Written by renowned authors, Shape-Memory Polymers and Multifunctional Composites is a broad overview of the systematic progress associated with this emerging class of materials. The book presents an overview of SMPs and a detailed discussion of their structural, thermo-mechanical, and electrical properties, and their applications in fields including aeronautics, astronautics, biomedicine, and the automotive industry. Covering topics ranging from synthesis procedures to ultimate applications, this is a sound instructional text that serves as a guide to smart materials and offers an in-depth exploration of multifunctional SMPs and SMP composites, outlining their important role in the materials field.
In each chapter, industry experts discuss different key aspects of novel smart materials, from their properties and fabrication to the actuation approaches used to trigger shape recovery. This comprehensive analysis explores the different functions of SMPs, the fundamentals behind them, and the ways in which polymers may reshape product design in general.
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Contents
Preface v
Editors vii
Contributors ix
1 Overview of Shape-Memory Polymers 1

1.1 Introduction 1
1.2 Defi nition of Actively Moving Polymers 2
1.3 Shape-Memory Polymer Architectures 3
1.4 Light-Induced Dual-Shape Effect 11
1.5 Triple-Shape Polymers 12
1.6 Outlook 14
References 15
2 The Structural Variety of Shape-Memory Polymers 21
2.1 Structural Requirements for SMP 22
2.2 SMPs with a Covalently Cross-Linked Primary Structure 24
2.3 Thermoplastic Shape-Memory Polymers 33
2.4 Remarks and Outlook 59
References 60
3 Thermomechanical Behavior and Modeling Approaches 65
3.1 Introduction 65
3.2 Modeling of Thermomechanical Behavior of SMPs 71
3.3 Conclusions 87
4 Thermomechanical Characterizations of Shape-Memory  Polymers (Dual/Triple-Shape) and Modeling Approaches 91
4.1 Introduction to the Thermally Induced Shape-Memory Effect of Polymers 91
4.2 Investigation of the Dual-Shape Effect of Shape-Memory Polymers with Cyclic, Thermomechanical Tensile Tests 93
4.3 Investigation of the Triple-Shape Effect of Shape-Memory Polymers with Cyclic, Thermomechanical Tensile Tests 98
4.4 Thermomechanical Model Approaches for Simulation of the Shape-Memory Behavior of Polymers 101
4.5 Summary and Outlook 104
References 105
5   Electrical, Thermomechanical, and Shape-Memory Properties  of the PU Shape-Memory Polymer Filled with Carbon Black 109
5.1 Introduction 110
5.2 Experiment 111
5.3 Results and Discussion 116
5.4 Conclusions 129
References 130
6 Multifunctional Shape-Memory Polymers and Actuation  Methods 133
6.1 Introduction 134
6.2 Thermal-Induced Shape-Memory Effect 135
6.3 Light-Induced Shape-Memory Effect 138
6.4 Electrically Induced Shape-Memory Effect 147
6.5 Solution-Driven Shape-Memory Effect 174
6.6 Summary and Outlook 196
References 197
7 Shape-Memory Polymer Composites 203
7.1 Introduction 203
7.2 Constitutive Relationship of Shape-Memory Polymers 204
7.3 Shape-Memory Polymer Composites 213
7.4 Summary and Outlook 229
References 229
8 Applications of Shape-Memory Polymers in Aerospace 233
8.1 Introduction 234
8.2 Shape-Memory Polymer Composite Hinge 234
8.3 Shape-Memory Polymer Composite Boom 240
8.4 Shape-Memory Polymer Composite for Deployable Optical Systems 242
8.5 Shape-Memory Polymer Composite for Ground-Based Deployable Mirrors 243
8.6 Shape-Memory Polymer Composite Refl ector 244
8.7 Shape-Memory Polymer for Morphing Structures 247
8.8 Reusable Shape-Memory Polymer Mandrel 262
8.9 Summary and Outlook 264
References 264
9 Shape-Memory Polymer Foam and Applications 267
9.1 Introduction 267
9.2 Overview of CHEM Foam Deployable Structure 269
9.3 CHEM Structure Space Applications 275
9.4 Potential Commercial Applications of CHEM Structures 285
9.5 Medical Applications of CHEM Structures 288
References 289
10 Shape-Memory Polymer Textile 293
10.1 Introduction 294
10.2 Overview of SMPs Used for Textiles 297
10.3 Importance of Textile 299
10.4 Main Physical Properties/Benefi ts of Textiles 300
10.5 Applications and Examples 308
References 312
11 Applications of Shape-Memory Polymers in Biomedicine 315
11.1 Introduction 315
11.2 Characteristics of Shape-Memory Polymers 316
11.3 Biomedical Applications of Shape-Memory Polymers 317
11.4 CHEM Foam Structures and Medical Applications 326
11.5 Summary and Outlook 329
References 329
12 Novel Applications and Future of Shape-Memory Polymers
12.1 Introduction 333
12.2 Concerns in Materials Selection and Design 334
12.3 Applications 337
12.4 Future Directions in Developing New SMPs and Applications 358
12.5 Conclusions 359
Acknowledgments 360
References 360
Index

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