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Expanded austenite by low temperature plasma nitriding of austenitic stainless steels pushes carbon ahead of the nitrided layer.
Apparently, this phenomenon accompanies uphill carbon diffusion. Clarifying the mechanism of this carbon push-ahead effect is important
for controlling treated-layer microstructure. This investigation is intended to clear the push-ahead effect of specimens treated with a
combination of carburizing and nitriding. Plasma treatments were carried out for 18Cr¨C8Ni steel in 667 Pa at 673 K. We used the
following gas-flow ratios: 80% N2¨C20% H2 for nitriding; Ar gas mixed with 5% CH4 for carburizing; and 80% N2 mixed with from 5%
CH4 and balancing H2 for simultaneous carburizing and nitriding. Glow-discharge optical emission spectroscopy (GDOES) indicated an
accumulated carbon layer beyond the nitrogen plateau on the nitrided specimen of pre-carburized sample. Such a carbon accumulation
profile also resulted from simultaneous treatment. Furthermore, carbon accumulated similarly in cases of carburizing after nitriding
treatment. Nitrided specimens of pre-carburized samples have a small carbon peak just under the surface on GDOES profile. This small
carbon peak weakened and disappeared with increasing nitriding time. X-ray diffraction analysis revealed formation of e (Fe2¨C3N) phase
just under the surface of the nitrided pre-carburized sample.
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