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Boron-containing Polymers
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¡¶Boron-containing Polymers¡·ÊôÓÚ¡¶Macromolecules Containing Metal and Metal-Like Elements¡·ÏµÁУ¬ËÑË÷¹ýСľ³æÉÏÖ»ÓÐÒ»¸öÁ´½Óµ½ÍâÃæ£¬¹ÊÒÔ¸½¼þÐÎʽ·ÖÏí¸ø´ó¼Ò¡£ googleͼÊéÀïҲûÓÐÏà¹Ø½éÉÜ£¬Ö»ºÃ°ÑÊéÀïÃæµÄ½éÉÜÌùÔÚÏÂÃæ¡£ Boron has been known as an element since its discovery in 1808 by Davy, Gay- Lussac, and Thenard, but it was not purified until 1909. The first polymers containing boron were synthesized by Stock about 80 years ago. Since then there has been a growing number and variety of boron-containing polymers produced. The emphasis for much of the development of boron polymers involves boron¡¯s ability for delocalizing electrons because of the presence of an empty p orbital. Furthermore, boron¡¯s ability to capture neutrons and its ability to form protective coatings have been driving forces to produce polymers. Finally, boron polymers with high percentages of nitrogen and boron have been sought as precursors to the ceramic boron nitride and boron nitride fibers. This volume presents the state-of-the-art developments with respect to boron-containing polymers. It captures the explosive development of these important materials in the areas of ceramics, coatings, nanomaterials, catalysts, therapeutic agents, and especially electronic applications such as nonlinear optical and fluorescent light-emitting materials. The chapters give supportive and historical developments that allow a person unfamiliar with boron polymers to appreciate and understand the topics presented. Practical application of boron-containing materials is also emphasized. Thanks to the efforts of the leading scientists in the fields represented, the full range of activity is included in this volume.[ Last edited by saladzhang on 2011-12-25 at 17:49 ] |
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