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Nanoporous Materials The current review article attempts to cover the Ž eld of nanoporous materials, thereby materials with voids of the order of 1 nm to 100 nm or even larger. Concepts, that have an effect on general basis, are introduced and the common features among the different classes of nanoporous materials are demonstrated enabling understanding their formation and stability. It is seen that most successful method to produce nanoporous materials made by design is to imprint a template structure into a functional inorganic or even organic network. Further, the manuscript gives an introduction to state of the art overview for microporous, mesoporous and macroporous materials, the preference lies on ordered pore structures. Further, it is demonstrated how important but demanding the use of modern analytical techniques are. This makes the eld of nanoporous materials truly interdisciplinary with aspects of inorganic chemistry, polymer science, colloid chemistry, physical chemistry, analytical chemistry and chemical engineering. Keywords: Porous Materials, Templating Concept, Ordered Mesoporous Structures. CONTENTS 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 581 1.1. General DeŽ nitions . . . . . . . . . . . . . . . . . . . . . . . . . 581 1.2. Relevance of Nanoporous Materials . . . . . . . . . . . . . . . 582 1.3. ClassiŽ cations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 582 1.4. Modern Analysis of Nanoporous Materials . . . . . . . . . . 584 2. General Strategies for Producing Porous Materials of Any Kind . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 589 3. Inorganic Porous Materials . . . . . . . . . . . . . . . . . . . . . . . 590 3.1. Microporous Materials . . . . . . . . . . . . . . . . . . . . . . . 590 3.2. Mesoporous Materials . . . . . . . . . . . . . . . . . . . . . . . 595 3.3. Macroporous Materials . . . . . . . . . . . . . . . . . . . . . . . 602 4. Organic Porous Materials . . . . . . . . . . . . . . . . . . . . . . . . 604 5. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 605 Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 605 References and Notes . . . . . . . . . . . . . . . . . . . . . . . . . . . 605 [ Last edited by popsheng on 2007-4-9 at 22:19 ] |
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4楼2006-11-24 08:21:37
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