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loser_zhuľ³æ (СÓÐÃûÆø)
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| It is evident from the NH3-TPD profiles (Fig. 4) that both AS and AM showed a broad peak in the temperature range of 120¨C250¡æ. However, the number of acid sites in AM is almost twice as compared to those present in AS. This could be one of the reasons for the higher conversion of AM in spite of having a lower surface area than AS. Further, sample AU has high surface area and stronger acid sites than AM and AS as indicated by the broad peak in the temperature range of 200¨C300¡æ which are labeled as MS (moderately strong acid sites). |
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°®ÓëÓêÏÂ(½ð±Ò+1): ~! 2011-08-20 09:38:35
sltmac(½ð±Ò+1): »¶Ó³£À´ 2011-08-20 09:48:49
loser_zhu(½ð±Ò+34, ·ÒëEPI+1): 2011-08-20 16:19:39
°®ÓëÓêÏÂ(½ð±Ò+1): ~! 2011-08-20 09:38:35
sltmac(½ð±Ò+1): »¶Ó³£À´ 2011-08-20 09:48:49
loser_zhu(½ð±Ò+34, ·ÒëEPI+1): 2011-08-20 16:19:39
| ÓÉNH3-TPDͼ£¨Í¼4£©¿ÉÒÔ¿´³öASºÍAMÔÚ120-250¡æ·¶Î§ÄÚ¾ùÓÐÒ»¸ö½Ï¿íµÄÍѸ½·å¡£È»¶ø£¬AMÉϵÄËáÖÐÐÄÊýÁ¿¼¸ºõÊÇASÉÏËáÖÐÐÄÊýÁ¿µÄÁ½±¶¡£ËäÈ»AMµÄ±È±íÃæ»ýСÓÚASµÄ±È±íÃæ»ý£¬µ«ÊÇËáÖÐÐÄÊýÁ¿¶à¿ÉÄÜÊÇAMÉϾßÓнϸ߻îÐÔµÄÔÒòÖ®Ò»¡£ÁíÍ⣬ÓëAMºÍAS±È½Ï£¬AU¾ßÓнϸߵıȱíÃæ»ýºÍ½ÏÇ¿µÄËáÐÔ£¨Í¼ÖÐMSÔÚ200-300¡æÖ®¼äÓÐÒ»¸ö½Ï¿íµÄÍѸ½·å£¬±»±êʾΪMS£¬¼´ÖеÈÇ¿¶ÈËáÖÐÐÄ£© |
2Â¥2011-08-20 09:10:29
phu_grassman
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°®ÓëÓêÏÂ(½ð±Ò+1): ~! 2011-08-20 09:38:46
sltmac(½ð±Ò+1): ר¼Ò¹ËÎÊÈÈÐÄ 2011-08-20 09:48:34
°®ÓëÓêÏÂ(½ð±Ò+1): ~! 2011-08-20 09:38:46
sltmac(½ð±Ò+1): ר¼Ò¹ËÎÊÈÈÐÄ 2011-08-20 09:48:34
|
It is evident from the NH3-TPD profiles (Fig. 4) that both AS and AM showed a broad peak in the temperature range of 120¨C250¡æ. However, the number of acid sites in AM is almost twice as compared to those present in AS. This could be one of the reasons for the higher conversion of AM in spite of having a lower surface area than AS. Further, sample AU has high surface area and stronger acid sites than AM and AS as indicated by the broad peak in the temperature range of 200¨C300¡æ which are labeled as MS (moderately strong acid sites). ´Óͼ4¸ø³öµÄNH3-TPDÆ×ͼ¿ÉÒÔÃ÷ÏԵĿ´³öASºÍAM¶¼ÔÚζÈΪ120¨C250¡æ¼ä³öÏÖÁË¿í·å¡£È»¶øAMÖеÃËáÖÐÐĵÄÊýÄ¿¼¸ºõÊÇASÖеÄÁ½±¶¡£ÕâÓпÉÄÜÊÇAMËäÈ»¾ßÓбÈAS¸üСµÄ±íÃæ»ý£¬µ«¾ßÓиü¸ßת»¯ÂʵÄÒ»¸öÔÒò¡£´ËÍâÔÚζÈ200¨C300¡æÖ®¼äµÄÒÔMS£¨ÖеÈÇ¿¶ÈµÄËá룩±ê¼ÇµÄ¿í·åÏÔʾ£¬ÑùÆ·AU¾ßÓдóµÄ±íÃæ»ýÒÔ¼°±ÈAMºÍAS¸üÇ¿µÄËáÖÐÐÄ¡£ |
3Â¥2011-08-20 09:19:25













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