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xpy111

铁杆木虫 (著名写手)

应助: 0 (幼儿园)
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散金: 60
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在线: 105.7小时
虫号: 199885
注册: 2006-02-27
性别: GG
专业: 生物医学传感

[交流] 【最新综述】Pd催化的Mizoroki-Heck and Suzuki-Miyaura Couplings 反应

【题目】On the Nature of the Active Species in Palladium Catalyzed Mizoroki-Heck and Suzuki-Miyaura Couplings - Homogeneous or Heterogeneous Catalysis, A Critical Review
【杂志】Adv. Synth. Catal. 2006, 348, 609 – 679
【内容】
1 Introduction
2 Mechanism
3 Homogeneous Precatalysts
3.1 Homogeneous Precatalysts with N, O, P or S
Donor Ligands
3.2 “Naked” Homogeneous Precatalysts
3.3 Palladacycle-Based Homogeneous Precatalysts
3.4 N-Heterocyclic Carbene-Containing Precatalysts
4 Heterogeneous Precatalysts
4.1 Pd(0) Particles on Oxide or Carbon Supports
4.2 Pd(II) Exchanged Supports
4.3 Supported Metal-Ligand Complexes
4.4 Soluble or Polymer Nanosphere-Supported Pd
Nanoparticle Precatalysts
4.5 Polymer or Oxide “Encapsulated” Precatalysts
5 Distinguishing Between Soluble vs. Insoluble,
Molecular vs. Nanoparticle Catalysts
5.1 Aryl Iodides vs. Bromides vs. Chlorides
5.2 Filtration or Split Tests
5.3 Kinetic Studies vs. Catalyst Recycle with Consistent
Yield
5.4 Reaction Selectivity
5.5 Correlation of Reaction Rate with Concentration
of Palladium in Solution
5.6 “Quantitative” Catalyst Recovery
5.7 Mercury Test
5.8 Selective Poisons for Solid Catalysts
5.9 Selective Poisons for Soluble Catalysts
5.10 3-Phase Test
6 Summary and Conclusions
【关键词】 CC coupling; colloidal particles; heterogeneous;
homogeneous; leaching; 3-phase test

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suggested by rabbit7708:
发帖格式不错，符合要求，本想加你金币了，但您的附件有问题，你是分卷压缩的。但是由于你上传的附件把后缀去掉了，还有文件名太长，所以不能解压，需要改一下，把文件名字数减少但三个文件要保证一致，并分别加上后缀.part1.rar，.part2.rar，.part3.rar，才能顺利解压，请及时前来改一下帖子的附件，以便虫友能顺利解压！不要浪费大家的金币，都是辛苦赚来的。我把改后的先加上了，请你把原来的删除！估计应该是你的操作失误，不是故意的。希望还是由您自己来改比较好！请尽快解决！谢谢！

再来下载的虫友请下载后三个文件，可以解压的。谢谢！

[ Last edited by wxwdoctor on 2007-3-25 at 20:44 ]

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