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taozhikai

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[资源] nature communications最新一期有机--量子点复合材料

With controlled nanometre-sized pores and surface areas of thousands of square metres per gram, metal-organic frameworks (MOmoFs) may have an integral role in future catalysis, filtration and sensing applications. In general, for MOmoF-based device fabrication, well-organized or patterned MOmoF growth is required, and thus conventional synthetic routes are not suitable. Mmoreover, to expand their applicability, the introduction of additional functionality into MOmoFs is desirable. Here, we explore the use of nanostructured poly-hydrate zinc phosphate
(α-hopeite) microparticles as nucleation seeds for that simultaneously address all these issues. Affording spatial control of nucleation and significantly accelerating MOmoF growth, these α-hopeite microparticles are found to act as nucleation agents both in solution and on solid surfaces. In addition, the introduction of functional nanoparticles (metallic, semiconducting, polymeric) into these nucleating seeds translates directly to the fabrication of functional MOmoFs suitable for molecular size-selective applications.

[ Last edited by 挥泪天使 on 2011-6-14 at 08:03 ]
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2011-06-13 23:49   回复  
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