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If combined with a geometry optimisation, the effect of these deletions on the C–Ge–C valence angle can be studied. These calculations were performed on the threemolecule cluster as explained earlier. It was found that removal of the ncl/s* Ge–Cl donation lowers the C–Ge–C angle from 123.48 to 121.08 Although this is still larger than the value of 118.88 found in the isolated molecule, one can only expect to observe a trend rather than obtain an accurate figure with this method. |
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