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The permeate obtained by ultrafiltration had ameasurable
CODvalue aswell as high salinity.Nevertheless, it is expected
to have a much lower oil content, as COD values include
soluble components such as small molecule acids that do
not contribute to the O&G measure, regulated for off-shore
disposal (29). As long as O&G limitations are met, UF may
be a sufficient method for the treatment of this stream. For
onshore wells, UF treatment would be a good choice for
pretreatment of this streambefore using ROorNF to remove
salts and small molecule contaminants.
        As described earlier, fouling is the limiting issue in the
use ofUFmembranes for producedwater treatment.Hence,
24 h dead-end fouling tests were conducted using PW-A as
the feed. Figure 1 shows the normalized flux versus time
data from such experiments for each membrane. During
the filtration of the produced water, the normalized flux of
the PAN/PAN-g-PEOblendmembrane remainedmuch above
that of the commercial PAN membrane. The drastic flux
decrease immediately upon contact with the foulant, ob-
served for the commercial membrane, is characteristic of
adsorptive fouling. The more gradual flux decrease for the
blendmembrane is typical for cake deposition (18, 30). After
24 h, the blend membrane lost 68% of its flux, whereas the
commercial PAN membrane lost 92%. In fact, even though
the initial PWP of the commercial PAN membrane was
approximately twice that of the PAN/PAN-g-PEO blend
membrane, its final flux was ∼40% lower. The total volume
of solution filtered through PAN-g-PEO blendmembrane in
this time period was 420mL vs 230mL for the control. Upon
switching to a water feed, both membranes recovered a
portion of their fluxes. The fact that the recovery was lower
for the PAN/PAN-g-PEO blend membrane could be due to
the formation of amore compact cake layer. After a backwash
to remove the cake layer, the PAN/PAN-g-PEO membranerecovered its initial flux completely. Backwashing is a
common physical cleaning method that allows for the
mechanical removal of accumulated particulates not strongly
adsorbed to the membrane surface. The complete recovery
of the initial flux indicates that even with this complex feed,
the blendmembrane resisted irreversible, adsorptive fouling,
the first demonstration of such for a polymericUFmembrane,
to the authors¡¯ knowledge. Under similar conditions, the
Sepro PAN-400 lost 37% of its flux irreversibly. The ability of
PAN/PAN-g-PEO blend UF membranes to better maintain
and recover their flux shows the distinct advantage of such
membranes over a commercial PANUFmembrane of similar
selectivity.

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