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lanlan1987金虫 (正式写手)
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The comments above underline that further studies will be needed to ascertain the origin of the selectivity differences observed by Tsang and co-workers. In particular, operando techniques need to be used, since Grunwaldt et al.showed that Cu wetted differently ZnO depending on the experimental conditions. It would be interesting to assess 1) possible changes in shape and size of the copper particles under reaction conditions, 2) the possibility of Zn–Cu surface alloys formation, and 3) the Cu surface area in situ after reaction (by N2O reactive frontal chromatography in the case of Cu–ZnO platelets and Cu–ZnO rods. |
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Mally89
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2楼2011-05-06 12:21:43
Mally89
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3楼2011-05-06 12:30:46
Mally89
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【答案】应助回帖
lanlan1987(金币+6): 2011-05-06 16:04:36
lanlan1987(金币+3): 2011-05-06 17:33:08
lanlan1987(金币+3): 2011-05-06 17:33:08
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It would be interesting to assess 1) possible changes in shape and size of the copper particles under reaction conditions, 2) the possibility of Zn–Cu surface alloys formation, and 3) the Cu surface area in situ after reaction by N2O reactive frontal chromatography in the case of Cu–ZnO platelets and Cu–ZnO rods. 这将会很有趣:1、可能改变反应条件下纳米级铜粉的形状和大小;2、可能形成Zn-Cu表面合金;3、通过在Cu-ZnO板和Cu-ZnO棒周围显示的N2O反应前沿色谱来判定反应后原位Cu表面积。 |
4楼2011-05-06 13:12:59










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