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[求助]
<36金币>求助几句话的翻译，附自己翻译（荧光方面的）
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比较两个配合物的发射光谱可以看出：配合物(2)的发射光谱较配合物(1)的发射谱带红移46nm，且发射峰明显增强，这可能是由于配合物(2)中所有配位原子都参与配位，使配体到中心离子的电荷迁移程度增加，导致发光谱带红移；同时配合物(2)的三维聚合物空间结构使其刚性进一步增加，减弱了荧光的非辐射振动淬灭，使发光强度进一步增大。 我自己的翻译: compared with the maximumemission of crystal 1, crystal 2 appeared spectral bands redshift(46nm), and the emission peak of crystal 2 is obvious enhancement. which can be tentatively assigned to that all the coordination atom of crystal 2 participated in the coordination reaction causing the extent increase of ligand-to-metal charge transfer (LMCT) , which caused spectral bands redshift. At the same time, crystal 2 have three dimensional spatial structure makes its rigid further increase, which weakened the fluorescent the radiation vibration quenches, which increase the intensity of fluorescence. [ Last edited by yinguojie on 2011-4-28 at 11:54 ] |
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考博求助
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2楼2011-04-28 11:56:36
风语河岸柳
木虫 (小有名气)
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【答案】应助回帖
yinguojie(金币+36, 翻译EPI+1): 谢谢~~~ 2011-04-29 17:09:32
| Compared with the maximum emission of crystal 1, crystal 2 appears spectral bands redshift(46nm), the emission peak of crystal 2 is obviously enhanced, which maybe attributed to that all the coordination atoms of crystal 2 participate in the coordination reaction, cause the extent increase of ligand-to-metal charge transfer (LMCT) , and lead to spectral bands redshift. At the same time, crystal 2 has 3D spatial structure making its rigid further increase, which weaken the radiation vibration quenches of fluorescence and increase the luminescence intensity . |
3楼2011-04-29 15:59:50
