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ypfkb(金币+5, 翻译EPI+1): 2011-04-14 09:24:25
ringzhu(金币+50): ~~ 2011-04-18 18:52:28
ringzhu(金币+50): ~~ 2011-04-18 18:53:01
ringzhu(金币+5): ~~ 2011-04-18 18:53:08

By verification of different dynamics models to have a conclude that the control step of catalytical dehydrogenation of NO on Cu/ZSM-5 is surface bimolecular reaction happened between two adsorbed NO moleculars, but also the sorption of NO on active sites is reversible and the decomposition reaction order for NO is 2,for O is negative number,respectively. Enriched Oxygen repress the decomposition reaction. Measuring the reaction activation energy is E=52kJ.mol-1 and the relationship between rate constant and temperuture T based on this dynamics models.

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