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★ 小木虫(金币+0.5):给个红包,谢谢回帖交流
曹荣研究员
曹荣,男,1966年8月生于福建长汀。现为中国科学院福建物质结构研究所副所长、研究员、博士生导师、学术委员会委员;结构化学国家重点实验室主任、学术委员会委员;《中国化学》、《无机化学学报》、《结构化学》编委,1986年毕业于中国科学技术大学近代化学系,1989年获中国科学院福建物质结构研究所硕士学位,1993年获中国科学院福建物质结构研究所博士学位后分配在物构所工作,1994年7月晋升为副研究员,1998年2月晋升为研究员、11月获博士生导师资格,曾在香港理工大学应用生物及化学科技系做博士后、日本名古屋大学物质科学国际研究中心做日本学术振兴会(JSPS)特别研究员。2002入选中国科学院福建物质结构研究所“百人计划”,2003年获国家杰出青年基金,2004年获政府特殊津贴,2006年入选“新世纪百千万人才工程”国家级人选。曾获中国青年科技奖(2006年)、中国化学会青年化学奖(1998年)、福建省青年科技奖(1998年)、运盛(福建)青年科技奖(2003年),作为主要完成者获国家自然科学奖二等奖一次(2002年,排名第三),中国科学院自然科学奖一等奖一次(2001年,排名第三)、二等奖一次(2000年,排名第二),发表SCI论文170多篇,论文被他人引用超过1600次。主要研究领域为无机-有机杂化材料及超分子化学、纳米分子材料、有机-无机复合膜及介孔材料等。承担了国家973计划、国家杰出青年基金、中科院“百人计划”、国家自然科学基金重大项目、重点项目、面上项目、青年项目、省自然科学基金重点项目、中国科学院重要方向性项目等多项研究课题。
联系电话:0591-83796710,电子邮件:rcao@fjirsm.ac.cn
代表作:
1、 Zhengang Guo, Rong Cao,* Xin Wang, Hongfang Li, Wenbing Yuan, Guojian Wang, Haohan Wu, Jing Li, A Multifunctional 3D Ferroelectric and NLO-active Porous Metal-organic Framework, J. Am. Chem. Soc., 131, 6894-6895 (2009).
2、 Liang, Yucang; Cao, Rong;* Su, Weiping; Hong, Maochun; Zhang, Wenjian. Syntheses, structures, and magnetic properties of two gadolinium(III)-copper(II) coordination polymers by a hydrothermal reaction, Angew. Chem., Int. Ed., 39(18), 3304-3307 (2000).
3、 Shuiying Gao, Daqiang Yuan, Jian Lü , Taohai Li and Rong Cao,* Multilayer films of single-component and charged tetraaminocalix[4]arenes based on hydrogen bonding, Chem. Commun., 1813–1815 (2007)
4、 Xiaoju Li, Rong Cao,* Zhengang Guo and Jian Lu¨, Hydroxyl-directed dinitration of carboxylate ligands mediated by lead and nickel nitrates and preparation of Pb/Ni heterometallic complexes under hydrothermal conditions, Chem. Commun., 1938–1940(2006).
5、 Wenhua Bi, Rong Cao*, Daofeng Sun, Daqiang Yuan, Xing Li, Yanqin Wang, Xiaoju Li and Maochun Hong Isomer separation, conformation control of flexible cyclohexanedicarboxylate ligand in cadmium complexes, Chem. Commun., 2104-2105 (2004).
主要论文
1. Yucang Liang, Rong Cao,* Weiping Su, Maochun Hong,* Wenjian Zhang, Syntheses, structures, and magnetic properties of two gadolinium(III)-copper(II) coordination polymers by a hydrothermal reaction, Angew. Chem., Int. Ed., 39(18), 3304-3307 (2000).
2. Weiping Su, Maochun Hong,* Jiabao Weng, Rong Cao,* Shaofang Lu, A semiconducting lamella polymer [{Ag(C5H4NS)}n] with a graphite-like array of silver(I) ions and its analogue with a layered structure, Angew. Chem., Int. Ed., 39(16), 2911-2914 (2000).
3. Maochun Hong,* Yingjun Zhao, Weiping Su, Rong Cao,* Makoto Fujita, Zhongyuan Zhou, Albert S. C. Chan, A silver(I) coordination polymer chain containing nanosized tubes with anionic and solvent molecule guests, Angew. Chem., Int. Ed., 39(14), 2468-2470 (2000).
4. Zhengang Guo, Rong Cao,* Xin Wang, Hongfang Li, Wenbing Yuan, Guojian Wang, Haohan Wu, Jing Li, A Multifunctional 3D Ferroelectric and NLO-active Porous Metal-organic Framework, J. Am. Chem. Soc., 131, 6894-6895 (2009).
5. Maochun Hong,* Yingjun Zhao, Weiping Su, Rong Cao,* Makoto Fujita, Zhongyuan Zhou, Albert S. C. Chan, A Nanometer-Sized Metallosupramolecular Cube with Oh Symmetry, J. Am. Chem. Soc., 122(19), 4819-4820 (2000).
6. Maochun Hong,* Weiping Su, Rong Cao,* Makoto Fujita, Jiaxi Lu, Assembly of silver(I) polymers with helical and lamellar structures. Chem.--Eur. J., 6(3), 427-431 (2000).
7. Shuiying Gao, Daqiang Yuan, Jian Lü , Taohai Li and Rong Cao,* Multilayer films of single-component and charged tetraaminocalix[4]arenes based on hydrogen bonding, Chem. Commun., 1813–1815 (2007).
8. Xiaoju Li, Rong Cao,* Zhengang Guo and Jian Lu¨, Hydroxyl-directed dinitration of carboxylate ligands mediated by lead and nickel nitrates and preparation of Pb/Ni heterometallic complexes under hydrothermal conditions, Chem. Commun., 1938–1940(2006)
9. Wenhua Bi, Rong Cao*, Daofeng Sun, Daqiang Yuan, Xing Li, Yanqin Wang, Xiaoju Li and Maochun Hong Isomer separation, conformation control of flexible cyclohexanedicarboxylate ligand in cadmium complexes, Chem. Commun., 2104-2105 (2004)
10. Daofeng Sun, Rong Cao,* Yanqiong Sun, Wenhua Bi, Daqiang Yuan, Qian Shi, Xing, Syntheses and structures of two novel copper complexes constructed by unusual planar tetracopper(II) SBUs, Chem. Commun., 1528 –1529 (2003)
11. Rong Cao, Kazuyuki Tatsumi, Use of dipotassium cyanamide for the synthesis of cyanoimido (NCN2-) complexes of tungsten and cobalt, Chem. Commun., 2144 (2002)
12. Rong Cao,* Weiping Su, Maochun Hong, Wenjian Zhang, Jiaxi Lu, Wing-Tak Wong, A novel polynuclear palladium(ii) complex with asymmetric coordination of palladium atoms, Chem. Commun., 2083-2084 (1998).
13. Jian Lü, Wen-Hua Bi, Fu-Xian Xiao, Stuart R. Batten*, Rong Cao,* Lanthanide Coordination Polymers Constructed from Infinite Rod-Shaped Secondary Building Units and Flexible Ligands, Chem.--Asia. J., 3, 542 (2008)
14. Shuiying Gao, Rong Cao,* Jian Lu, Guoliang Li, Yafeng Li and Hongxun Yang, Photocatalytic properties of polyoxometalate–thionine composite films immobilized into microspheres under sunlight irradiation, J.Mater. Chem., 19, 4157–4163 (2009)
15. Taohai Li, Feng Li, Jian Lü, Zhengang Guo, Shuiying Gao, Rong Cao,* A Pentadecatungstate with Dinuclear Cerium(III) unit: Synthesis, Crystal Structure and Properties, Inorg. Chem.,47, 5612-5615(2008)
16. Xiao-Ju Li, Xin-Yi Wang, Song Gao,* and Rong Cao*, Two Three-Dimensional Metal-Organic Frameworks Containing One-Dimensional Hydroxyl/Carboxylate Mixed Bridged Metal Chains: Syntheses, Crystal Structures, and Magnetic Properties, Inorg. Chem., 45, 1508-1516(2006)
17. Daofeng Sun, Rong Cao,* Yanqiong Sun, Wenhua Bi, Xiaoju Li, Yanqin Wang, Qian Shi, and Xing Li, Novel silver-containing supramolecular frameworks constructed by combination of coordination bonds and supramolecular interactions, Inorg. Chem., 42, 7512-7518 (2003)
18. Rong Cao,* Qian Shi, Daofeng Sun, Maochun Hong, Wenghua Bi, and Yingjun Zhao, Syntheses and Characterizations of Copper(II) Polymeric Complexes Constructed from 1,2,4,5-Benzenetetracarboxylic Acid, Inorg. Chem., 41, 6161-6168 (2002)
19. Rong Cao, Kazuyuki Tatsumi, Alkylation Reactions of [WS4]2- and [h5-C5Me5]WS3]- with 2,6-Bis(bromomethyl)pyridine: The First Isolation of Bisalkylated Tetrathiometalate WS2{2,6-(SCH2)2(C5H3N)}, Inorg. Chem., 41, 4102-4104 (2002)
20. Rong Cao, Daofeng Sun, Yucang Liang, Maochun Hong, Tatsumi Kazuyuki, Qian Shi, Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid, Inorg. Chem., 41, 2087-2094 (2002).
21. Yucang Liang, Maochun Hong, Weiping Su, Rong Cao,* Wenjian Zhang, Preparations, Structures, and Magnetic Properties of a Series of Novel Copper(II)-Lanthanide (III) Coordination Polymers via Hydrothermal reaction, Inorg. Chem., 40, 4574-4582 (2001).
22. Hongxun Yang, Shengping Guo, Jun Tao, Jinxiang Lin, and Rong Cao*, Hydrothermal syntheses, Crystal structures, and Magnetic properties of a series of complexes constructed from multinuclear copper clusters and polyoxometalates, Crystal Growth & Design, 9, 3003-3005(2009)
23. Bo Xu, Jian Lü, and Rong Cao,* Anion-assisted Structural Variation of Cadmium Coordination Polymers: from 2D→3D Inclined Polycatenation to 2D→3D Polythreading, Crystal Growth & Design, 9, in press(2009)
24. Hongxun Yang, Jingxiang Lin, Jiutong Chen, Xiandong Zhu, Shuiying Gao, and Rong Cao,* A novel 1D chain compound constructed from alternating Wells-Dawson polyanions and mixed valence hexacopper phosphate cations, Crystal Growth & Design, 8, 2623-2625(2008)
25. Xiandong Zhu, Jian Lü, Xiaoju Li, Shuiying Gao, Guoliang Li, Fuxian Xiao, Rong Cao,* Luminescence of Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands, Crystal Growth & Design, 8, 1897-1901(2008)
26. Feng Li, Taohai Li, Xiaoju Li, Xing Li, Yuling Wang, and Rong Cao*, Synthesis of Chiral Coordination Polymers by Spontaneous Resolution, Crystal Growth & Design, 6, 1458-1462 (2006)
27. Yu-Ling Wang, Da-Qiang Yuan, Wen-Hua Bi, Xing Li, Xiao-Ju Li, Feng Li, and Rong Cao,* Syntheses and Characterizations of Two Novel 3-D Cobalt–Organic Frameworks from 2-D Honeycomb Building Blocks, Crystal Growth & Design, 5, 1849-1855 (2005)
28. Xiaoju Li, Rong Cao*, Wenhua Bi, Yanqin Wang, Yuling Wang, Xing Li, Zhengang Guo, A New Family of Cadmium(II) Coordination Polymers from Co-ligands: Effect of the Coexistent Groups (R = H, -NO2, -OH) on Crystal Structures and Properties, Crystal Growth & Design, 5, 1651-1656 (2005)
29. Xing Li, Rong Cao,* Yan Q. Sun, Qian Shi, Da Q. Yuan, Dao F. Sun, Wen H. Bi, and Mao C. Hong, Syntheses and Characterizations of Coordination Polymers Constructed from 4-Pyridylacetic Acid, Crystal Growth & Design, 4, 255-261(2004)
30. Xiaoju Li, Rong Cao,* Daofeng Sun, Wenhua Bi, Yanqin Wang, Xing Li, and Maochun Hong, Syntheses and Characterizations of Zinc(II) Compounds Containing Three-Dimensional Interpenetrating Diamondoid Networks Constructed by Mixed Ligands, Crystal Growth & Design, 4, 775-780(2004)
31. Maochun Hong, Weiping Su, Rong Cao,* Wenjian Zhang, Jiaxi Lu, Controlled Assembly Based on Multibridging Thiolate Ligands: New Polymeric Silver(I) Complexes with One-Dimensional Chain and Three-Dimensional Network Structures. Inorg. Chem., 38(3), 600-602 (1999).
32. Jian Lü, Wen-Hua Bi, and Rong Cao*, Observation of The Least Stable Conformer of 1,4-Cyclohexanedicarboxylic Anions in A Samarium Coordination Architecture, CrystEngComm, 11, in press(2009)
33. Tianfu Liu, Jian Lu, Linxi Shi, Zhengang Guo, Rong Cao,* Conformation control of a flexible 1,4-phenylenediacetate ligand in coordination complexes: a rigidity-modulated strategy, CrystEngComm, 11, 583-588(2009)
34. Rong Cao*, Jian Lü, Stuart R. Batten,* Copper 5-Sulfoisophthalato Quasi-planar Squares in Coordination Polymers Modulated by Alkaline-earth Metals: A Way to Molecular Squares? , CrystEngComm, 10, 784-789(2008).
35. Xiandong Zhu, Zhen Ma, Wenhua Bi, Yuling Wang, Daqiang Yuan, Rong Cao,* Formation of Sandwich-type Supercomplex through Second-sphere Coordination of Functionalized Macrocyclic Polyamines, CrystEngComm, 10, 19-22(2008).
36. Feng Li, Zhen Ma, Yuling Wang, Rong Cao,* Wenhua Bi and Xing Li, Exploring the synthesis of infinite helical chains with 2-carboxycinnamic acid, CrystEngComm, 7, 569–574(2005)
37. Jian Lu, Shui-Ying Gao, Jing-Xiang Lin, Lin-Xi Shi, Rong Cao,* Stuart R. Batten, Systematic investigation on the coordination chemistry of a sulfonated monoazo dye: Ligand-dominated d- and f-block derivatives, Dalton Trans., 1944-1953 (2009)
38. Jing-Xiang Lin, Jian Lu, Rong Cao,* Jiu-Tong Chen, Cheng-Yong Su, Supramolecular assembly from decavanadate anion and decamethylcucurbit[5]uril, Dalton Trans., 1101-1103 (2009)
39. Daofeng Sun, Rong Cao,* Yucang Liang, Qian Shi, Maochun Hong, Syntheses, crystal structures and sroperties of two novel lanthanide-carboxylate polymeric complexes, J. Chem. Soc., Dalton Trans., 1847-1851 (2002).
40. Yingjun Zhao, Maochun Hong, Daofeng Sun, Rong Cao,* A novel coordination polymer containing puckered rhombus grids, J. Chem. Soc., Dalton Trans., 1354-1357 (2002)
41. Daofeng Sun, Rong Cao,* Jiabao Weng, Maochun Hong, Yucang Liang, A novel luminescent 3D polymer containing silver chains formed by ligand unsupported Ag-Ag interactions and organic spacers, J. Chem. Soc., Dalton Trans., 291-292 (2002).
42. Daofeng Sun, Rong Cao,* Yucang Liang, Qian Shi, Weiping Su, Maochun Hong. Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures, J. Chem. Soc., Dalton Trans., 2335-2340 (2001).
43. Xiaoling Fan, Rong Cao,* Maochun Hong, Weiping Su, Daofeng Sun, A novel trinuclear cobalt complex comprising moieties of single and double C-S bond cleavage of diethydithiocarbamate, J. Chem. Soc., Dalton Trans., 2961-2962 (2001).
44. Yingjun Zhao, Maochun Hong, Weiping Su, Rong Cao,* Zhongyuan Zhou, Albert S. C. Chan, Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units, J. Chem. Soc., Dalton Trans., 1685-1686 (2000).
45. Weiping Su, Rong Cao,* Maochun Hong, Daxu Wu, Jiaxi Lu, A new access to palladium-phosphine chemistry. Formation of polynuclear palladium compounds via the oxidation of ligands in simple palladium(II) complexes, J. Chem. Soc., Dalton Trans., 1527-1532 (2000).
46. Rong Cao, Maochun Hong, Feilong Jiang, Xiulan Xie, Hanqin Liu, Syntheses and crystal structures of nickel(II) complexes with thiolate or/and phosphine ligands. J. Chem. Soc., Dalton Trans., 3459-63 (1994). |
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