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| 在低电位扫描速度或低浓度下，NiC12(bpy)3的电还原过程分三步进行，首先反应生成的是[Ni(+1)(bpy)3]1+，然后进一步电还原为Ni(0)(bpy)3，最后反应生成为[Ni(-1)(bpy)3]－。当达到一定扫速或浓度时，NiC12(bpy)3直接在电极上得到两个电子电还原为Ni(0)(bpy)3。 |
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yanjiu08(金币+9, 翻译EPI+1):谢谢 2011-01-09 16:12:21
| In the condition of low potential scan rate and low concentration, the reduction of NiC12(bpy)3 underwent three stages apparently. It was reduced by a one-electron process to [Ni(+1)(bpy)3]1+ for the first. The second, more negative reaction was assigned to the one-electron reduction of the resultant [Ni(+1)(bpy)3]1+ to [Ni(0)(bpy)3].The last, it was reduced to [Ni(-1)(bpy)3]－.when scan rate or the concentration of NiCl2(bpy)3 to reach a certain extent, NiC12(bpy)3 was reduced by a two-electron process to [Ni(0)(bpy)3]. |
2楼2011-01-09 14:09:21
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yanjiu08(金币+1): 2011-01-09 16:12:25
ringzhu(金币+2):欢迎常来翻译版哦~~O(∩_∩)O~ 2011-01-10 11:13:46
yanjiu08(金币+1): 2011-01-09 16:12:25
ringzhu(金币+2):欢迎常来翻译版哦~~O(∩_∩)O~ 2011-01-10 11:13:46
| For NiC12 (bpy) 3 , the procedure of power reduction are in three steps at low potential scan speed or low concentrations .The first reactant is [Ni (+1) (bpy) 3] 1 +, and then further reduced to Ni (0) (bpy) 3, finally generated [Ni (-1) (bpy) 3] -. Additionally ,NiC12 (bpy) 3 directly reduced to Ni (0) (bpy) 3 by obtain two electrons from the electrode when the scan rate or concentration reaches a certain concentration. |
3楼2011-01-09 14:16:56
