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北京石油化工学院2026年研究生招生接收调剂公告
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wangchun8ha

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[资源] 【分享】呵呵,Nature上看到的一篇新闻线

Surface-mediated chain reaction through
dissociative attachment
Tingbin Lim1,JohnC.Polanyi1*,HongGuo2and Wei Ji2
Chain reactions on a surface offer an important route to linear nanopatterning. We recently reported cooperative reactions
on a silicon surface in which the reaction of one halogen atom with a silicon atom of a silicon dimer induced the
halogenation of its neighbouring silicon atom through surface-mediated charge transfer. The reaction was unable to
propagate further but here we describe how, by chemically bridging the gaps between the rows of these silicon dimers,
this mechanism is able to form extended chains. The agents for chain growth are CH3Cl molecules that dissociatively
attach CH3groups and chlorine atoms to silicon atoms from different dimers. By means of charge transfer through the
surface, this gives rise to dangling bonds adjacent to the CH3groups and chlorine atoms (in effect, ‘free radicals’) that
dissociate further incoming CH3Cl molecules, thereby providing the growing points for chains of inde?nite length. This
versatile mechanism of chain growth is examined in experiments and using ab initio theory.
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http://www.namipan.com/d/nchem.930.pdf/
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wangchun8ha

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谢谢提醒
我再试试
2楼2010-12-17 18:31:05
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wangchun8ha

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3楼2010-12-17 18:36:27
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oolong1978

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无法链接,请lz再检查下。
4楼2010-12-21 21:03:50
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飞天超人

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★★★★★ 五星级,优秀推荐

没有啊~~~
5楼2010-12-21 22:50:56
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wangchun8ha

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怎么从纳米机器人上弄链接啊
6楼2010-12-22 10:19:55
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wangchun8ha

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7楼2010-12-22 10:29:01
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wangchun8ha

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301a8eb91e3581445db2cc12bc26c6cc0ee7e622e6a61e00
8楼2010-12-22 10:29:44
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wangchun8ha

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对不起,还是不会呜呜
9楼2010-12-22 10:31:02
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