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2Â¥2010-11-15 11:00:39
wumeng-wm
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- ½ð±Ò: 1337.8
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3Â¥2010-11-15 13:19:53
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4Â¥2010-11-15 13:23:13
petrocatal
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5Â¥2010-11-15 14:10:03
petrocatal
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- ·ÒëEPI: 134
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- ¹ó±ö: 0.01
- ½ð±Ò: 3436.6
- Ìû×Ó: 959
- ÔÚÏß: 299.5Сʱ
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| Desulfurization ash is by-products of flue gas desulfurization in coal-combustion and metallurgical industries. Arbitrarily stacking of the ash could result in plentiful of land occupation, serious secondary pollution and economic burden to the companies. With grinding thin coal as fuel, modern boilers produce huge fly ash emissions, which not only threatens our living environment but also limit the sustainable development of national economy. In this paper, desulphurization ash and fly ash are utilized to produce Sulfuric acid and alumina due to the scarce of sulphur and bauxite resources in china. Such approach could either promote the improvement of the people's living environment and alleviate the status of resource shortage, or satisfy industrialization demand and high efficiently utilize resources by recycling of useful resources. |
6Â¥2010-11-15 14:45:32
wumeng-wm
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- ·ÒëEPI: 6
- Ó¦Öú: 1 (Ó×¶ùÔ°)
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|
±¾Ñо¿µÄÖ÷ÒªÄÚÈݰüÀ¨£º(1)ÀûÓÃXRD¡¢DSC¡¢SEM¡¢EDSµÈ·½·¨Ñо¿ÍÑÁò»ÒµÄÎï»¯ÌØÐÔ¡¢¿óÎï×é³ÉÒÔ¼°Î¢¹ÛÐÎò£»(2)·ÖÎöÍÑÁò»ÒÖÆÁòËá-·Ûú»ÒÌáÈ¡Ñõ»¯ÂÁ¹ý³ÌµÄ·´Ó¦ÈÈÁ¦Ñ§£¬Åжϻ¯Ñ§·´Ó¦½øÐеĿÉÄÜÐÔ¡¢ÏȺó˳Ðò£¬·´Ó¦µÄƽºâÌõ¼þ¼°×îÖÕ·´Ó¦²úÎ(3)̽ÌÖ½¹Ì¿²ôÁ¿¡¢·Ûú»Ò²ôÁ¿¡¢ìÑÉÕζȵȶÔCaSO4µÄ·Ö½âºÍÂÁµÄ½þÌáµÄÓ°Ï죻(4)È·¶¨×î¼Ñ·´Ó¦Ìõ¼þ¡£ This paper is focused on 1) Physical and chemical characteristics,mineral composition and microstructure of the desulfurization ash were studied with methods of XRD¡¢DSC¡¢SEM¡¢EDS etc. (2) The process of producing sulfuric acid and alumina from desulfurization ash and fly ash respectively is studied on the basis of thermodynamics analysis, and the possibility,order,equilibrium condition and final products of the chemical reactions were all studied in this paper.(3) In addition to the mixing amounts of coke and fly ash ,the calcination temperature on the ecomposition of CaSO4 and the leaching of aluminium is also investigated in this paper.(4) The optimum reaction conditions were determined in the end. |
7Â¥2010-11-15 16:09:00
wumeng-wm
½ð³æ (ÕýʽдÊÖ)
- ·ÒëEPI: 6
- Ó¦Öú: 1 (Ó×¶ùÔ°)
- ½ð±Ò: 1337.8
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muyaqin(½ð±Ò+5, ·ÒëEPI+1): 2010-11-15 16:47:15
|
Desulfurization ash is by-products produced by flue gas desulfurization in coal-firing and metallurgical industries.Arbitrarily stacked desulfurization ash can occupy much of the land , cause serious secondary pollution, and bring great economic burden for companies.By adopting grinding thin coal as fuel ,modern boilers produce huge fly ash emissions,which not only greatly endanger our living environment but also enormously constrain the Sustainable development of national economy.Considering our country is in short of sulphur and bauxite resources,in this paper desulphurization ash and fly ash are used to produce Sulfuric acid and alumina,which not only improved the people's living environment, but also recycle useful resource to satisfy industrialization demand, alleviate resource shortage, and reach reutilization purpose. This paper is focused on 1) Physical and chemical characteristics,mineral composition and microstructure of the desulfurization ash were studied with methods of XRD¡¢DSC¡¢SEM¡¢EDS etc. (2) The process of producing sulfuric acid and alumina from desulfurization ash and fly ash respectively is studied on the basis of thermodynamics analysis, and the possibility,order,equilibrium condition and final products of the chemical reactions were all studied in this paper.(3) In addition to the mixing amounts of coke and fly ash ,the calcination temperature on the ecomposition of CaSO4 and the leaching of aluminium is also investigated in this paper.(4) The optimum reaction conditions were determined in the end. |
8Â¥2010-11-15 16:11:10
9Â¥2010-11-15 16:40:37
10Â¥2010-11-15 16:43:20
11Â¥2010-11-15 16:45:31
wumeng-wm
½ð³æ (ÕýʽдÊÖ)
- ·ÒëEPI: 6
- Ó¦Öú: 1 (Ó×¶ùÔ°)
- ½ð±Ò: 1337.8
- Ìû×Ó: 347
- ÔÚÏß: 79.1Сʱ
- ³æºÅ: 791911
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ͨ¹ýÑо¿¿ÉÒԵóö£º(1)ÍÑÁò»ÒµÄÖ÷Òª»¯Ñ§³É·ÖÊÇCaSO3¡¢CaSO4¡¢Ca(OH)2ºÍCaCO3£¬²¢º¬ÓÐÒ»¶¨Á¿µÄSiO2ºÍAl2O3µÈ£¬ÆäÖ÷Òª¿óÎïÏàΪ°ëË®ÑÇÁòËá¸Æ¡¢¶þˮʯ¸à¡¢·½½âʯ¡¢ôǸÆÊ¯£¬ÒÔ¼°ÉÙÁ¿ÂÈ»¯¸Æ£¬ÍÑÁò»ÒµÄ¿ÅÁ£ÐÎ×´²»¹æÔò£¬³ÊËéм״£¬Á£¶È±ä»¯²îÒì½Ï´ó£»(2)±¾Ñо¿µÄ·´Ó¦Ìåϵ¸´ÔÓ£¬Ö÷·´Ó¦ÔÚ800¡ãCʱ¿ªÊ¼·¢Éú£¬µ±´ïµ½900¡ãCÒÔÉÏʱ£¬Ëæ×ÅζȵÄÔö¼Ó£¬¸Ã·´Ó¦Ïà¶ÔÆäËû¸±·´Ó¦¸üÈÝÒ×·¢Éú£»(3)»¹Ô¼Á½¹Ì¿µÄ¼ÓÈë¿ÉÒÔÃ÷ÏÔ´Ù½øCaSO4µÄ·Ö½â£¬µ«Æä²ôÈëÁ¿²¢²»ÊÇÔ½¶àÔ½ºÃ£¬¶øÊÇÓÐÒ»¸öÁÙ½çÖµ£¬¸ßÓÚ´ËÁÙ½çÖµ»áÒÖÖÆCaSO4µÄ·Ö½â£¬·Ûú»ÒÖеÄAl2O3ºÍSiO2»áÓëCaSO4·Ö½â²úÉúµÄCaO·¢Éú¸´ÔӵĻ¯Ñ§·´Ó¦£¬ÔÚÉú³ÉC12A7µÄͬʱÉú³É¶àÖÖº¬Áò¸±²úÎӰÏìCaSO4µÄ·Ö½â£¬·Ûú»Ò²ôÁ¿¸ßʱ»á½µµÍÂÁµÄ½þÌáÂÊ£¬Î¶ÈÔ½¸ßÔ½ÓÐÀûÓÚCaSO4µÄ·Ö½âºÍÂÁµÄ½þÌᣬÑо¿ÖÐÓ°ÏìÒòËØµÄ˳ÐòΪζȣ¾·Ûú»Ò²ôÁ¿£¾½¹Ì¿²ôÁ¿£»(4)ÔÚе÷CaSO4µÄ·Ö½âÂʺÍÂÁµÄ½þÌáÂÊÖ®¼äƽºâµÄÇé¿öÏÂ×î¼ÑʵÑéÌõ¼þΪ1200¡ãC£¬C/DF1=0.085£¬Ash/DF1=0.294¡£ Four conclusions can be drawn from this study: (1)With a certain quantity of SiO2 and Al2O3,the main chemical compositions of the desulfurization ash include CaSO3,CaSO4,Ca(OH)2 and CaCO3 etc.Half water calcium sulfate,dehydrate gypsum,calcite and portlandite are the main mineral phases in the the desulfurization ash,and some calcium chloride is also found in the system.The grains in the desulfurization ash occur as clastic particles,with irregular particle shapes and different particle sizes .(2) The reaction system studied in this paper possess great complexity due to the appearance of some side reactions.The main reaction is triggered at 800¡ãC,and with the rise of temperature the main reaction is more and more likely to occur.when the temperature rise to 900¡ãC,compared with other side reactions the main reaction is more likely to occur and become the dominant reaction.(3)With the resistant coke adding to the system,the decomposition of CaSO4 is apparently accelerated,while there is a optimal amount of coke when the mixing amounts exceed the optimal amount it will bring the opposite effect.The Al2O3 and SiO2 react with the CaO from the decomposition of CaSO4 and trigger complicated reaction,producing C12A7 and other sulfur-containing by-products,which affect the decomposition of CaSO4 .High fly ash content will lower the producing of aluminium,while the rising of the temperature the is good for the decomposition of CaSO4 and the producing of aluminium.According to the importance of each influencing factor,the can be ordered as follows:temperature>fly ash content>coke content.(4)Considering the decomposition of CaSO4 and the producing of aluminium,the optimum conditions of the system is established as follows :1200¡ãC,C/DF1=0.085£¬Ash/DF1=0.294. Ñо¿±íÃ÷£¬²ÉÓÃÍÑÁò»ÒÖÆÈ¡ÁòËá-·Ûú»ÒÌáÈ¡Ñõ»¯ÂÁ¿ÉÒÔ´ïµ½½Ï¸ßµÄCaSO4·Ö½âÂʺÍÂÁµÄ½þÌáÂÊ£¬´Ë·½·¨´¦ÀíÍÑÁò»ÒºÍ·Ûú»Ò¾ßÓйãÀ«µÄÓ¦ÓÃǰ¾°¡£ The study in this paper shows that using desulphurization ash and fly ash to produce alumina can accomplish high decomposition rate of CaSO4 and extraction rate of aluminium,which reflect its vast application prospects in the disposition of desulphurization ash and fly ash. |
12Â¥2010-11-16 15:45:22
13Â¥2010-11-16 16:25:17














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1) Physical and chemical characteristics,mineral composition and microstructure of the desulfurization ash were studied with methods of XRD¡¢DSC¡¢SEM¡¢EDS etc. (2) The process of producing sulfuric acid and alumina from desulfurization ash and fly ash respectively is studied on the basis of thermodynamics analysis, and the possibility,order,equilibrium condition and final products of the chemical reactions were all studied in this paper.(3) In addition to the mixing amounts of coke and fly ash ,the calcination temperature on the ecomposition of CaSO4 and the leaching of aluminium is also investigated in this paper.(4) The optimum reaction conditions were determined in the end.
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