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lovelva3000(½ð±Ò+100, ·­ÒëEPI+1): 2010-11-09 22:26:08
The oxidation behavior of HPbO2- on anodes was studied on alkali media, though the DC resistance method. It was found that HPbO2- was conversed into PbO2 on anodes with the voltage value about 0.6v. However, with the anodic voltage value more than 0.8v, main anodic reaction is O2 releasing, accompanied with the former reaction. Electronically oxidated kinetic parameters, i0 and Bn, were measured with the steady polarization and Tafel response curves, equal to 10-0.528 and 0.24, respectively. The diffusion coefficient D of HPbO2- was 6.66*106, determined by the timed electronic method. ÓÐЩÖÐÎÄÓï¾ä´ÎÐò½øÐÐÁ˵÷Õû£¬Ä¿±êÓë½á¹ûÒª·Ö¿ª¡£
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Anodic oxidation behavior of HPbO2- in alkaline medium was studied in this paper
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The oxidation behavior of HPbO2- on anodes was studied on alkali media, though the DC resistance method. It was found that HPbO2- was conversed into PbO2 on anodes with the voltage value about 0.6v. However, with the anodic voltage value more than 0.8v, main anodic reaction is O2 releasing, accompanied with the former reaction. Electronically oxidated kinetic parameters, i0 and Bn, are measured with the steady polarization and Tafel response curves, equal to 10-0.528 and 0.24, respectively. The diffusion coefficient D of HPbO2- was 6.66*106, determined by the timed electronic method. ÓÐЩÖÐÎÄÓï¾ä´ÎÐò½øÐÐÁ˵÷Õû£¬Ä¿±êÓë½á¹ûÒª·Ö¿ª¡£
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