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1.AAB-Sequence Living Radical Chain Copolymerization of Naturally Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer 2.Here, we report the quantitative and highly selective 1:2 sequence-regulated radical copolymerization of naturally occurring (+)-d-limonene (L) and a maleimide (M) in fluoroalcohol giving chiral copolymers with high glass transition temperatures (220-250 ) originating from the specific rigid cyclic structures of the monomers. 3.A few examples were reported only for its radical copolymerizations with polar monomers, such as maleic anhydride and acrylates, which resulted in cyclocopolymerization or quite low consumption of Lim along with its low incorporation into the copolymers. 4.2-methyl-1-penetene 5.circular dichroisms |
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1988lang
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- ×¢²á: 2009-04-24
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