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【资源】Heterogenized Homogeneous Catalysts for Fine Chemicals Production
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Heterogenized Homogeneous Catalysts for Fine Chemicals Production: Materials and Processes (Catalysis by Metal Complexes) ![]() Heterogenized Homogeneous Catalysts for Fine Chemicals Production: Materials and Processes (Catalysis by Metal Complexes) By Pierluigi Barbaro, Francesca Liguori * Publisher: Springer * Number Of Pages: 400 * Publication Date: 2010-09-08 * ISBN-10 / ASIN: 9048136954 * ISBN-13 / EAN: 9789048136957 Product Description: This book provides the reader with the latest directions in the field of homogeneous catalysts for fine chemical production. Each theme is introduced from a broad perspective: materials, strategies, techniques and processes are presented both from a theoretical and a practical point of view. The focus is on those catalysts - particularly heterogenized homogeneous catalysts - and applications leading to the production of fine and speciality chemicals in a highly selective manner and with minimal environmental and economic impact. Each topic is treated critically so topics such as factors affecting the catalysts performance, the influence of the support, the catalysts' deactivation, the metal leaching or the issues on recycling are analyzed. Industrial and academic points of view are integrated and the feasibility and timeliness of industrial applications are illustrated. The reader is also provided with a comparison between parent heterogeneous and homogeneous systems. Heterogenized Homogeneous Catalysts for Fine Chemicals Production Materials and Processes Series: Catalysis by Metal Complexes, Vol. 33 Barbaro, Pierluigi; Liguori, Francesca (Eds.) 1st Edition., 2010, XVII, 400 p., Hardcover ISBN: 978-90-481-3695-7 * About this book This book provides the reader with the latest directions in the field of homogeneous catalysts for fine chemical production. Each theme is introduced from a broad perspective: materials, strategies, techniques and processes are presented both from a theoretical and a practical point of view. The focus is on those catalysts - particularly heterogenized homogeneous catalysts - and applications leading to the production of fine and speciality chemicals in a highly selective manner and with minimal environmental and economic impact. Each topic is treated critically so topics such as factors affecting the catalysts performance, the influence of the support, the catalysts' deactivation, the metal leaching or the issues on recycling are analyzed. Industrial and academic points of view are integrated and the feasibility and timeliness of industrial applications are illustrated. The reader is also provided with a comparison between parent heterogeneous and homogeneous systems. Content Level » Research Keywords » Carbonylation reactions - Fine chemical synthesis - Fine chemicals production - Heterogenized homogeneous catalysts - Inorganic supports - Organic supports Related subjects » Chemistry - Organic Chemistry - Physical Chemistry Contents Foreword: So Why Do We Need Supported Catalysts? .............................. v Preface .............................................................................................................. xi 1 Fine Chemicals Synthesis Through Heterogenized Catalysts: Scopes, Challenges and Needs .................................................................. 1 Duncan Macquarrie 2 Biomimetic Single-Site Heterogeneous Catalysts: Design Strategies and Catalytic Potential ............................................... 37 David Xuereb, Joanna Dzierzak, and Robert Raja 3 Heterogenization on Inorganic Supports: Methods and Applications ........................................................................................ 65 José M. Fraile, José I. García, José A. Mayoral, and Elisabet Pires 4 Covalent Heterogenization of Asymmetric Catalysts on Polymers and Nanoparticles ............................................................... 123 Ciril Jimeno, Sonia Sayalero, and Miquel A. Pericàs 5 Heterogenization of Homogeneous Catalysts on Dendrimers............... 171 Vital A. Yazerski and Robertus J.M. Klein Gebbink 6 Catalytic Membranes Embedding Selective Catalysts: Preparation and Applications .................................................................. 203 Enrico Drioli and Enrica Fontananova 7 Immobilized Complexes for Enantioselective Catalysis: the Industrial Perspective ......................................................................... 231 Benoît Pugin and Hans-Ulrich Blaser 8 Chemical Reaction Engineering Aspects for Heterogenized Molecular Catalysts .................................................................................. 247 Albert Renken 9 Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes .................................................................... 283 Agnes Zsigmond, Ferenc Notheisz, Petr Kluson, and Tomas Floris 10 Oxidations Mediated by Heterogenized Catalysts ............................... 361 Paulo Forte and Dirk De Vos 11 Heterogeneous Initiators for Sustainable Polymerization Processes ....................................................................... 385 Matthew D. Jones 12 Reactivity and Selectivity of Heterogenized Homogeneous Catalysts: Insights from Molecular Simulations ......... 413 Kourosh Malek and Rutger A. Van Santen 13 Instrumental Techniques for the Investigation of Heterogenised Catalysts: Characterisation and In situ Studies ................................................................................... 433 John Evans and Moniek Tromp Index ................................................................................................................. 449 http://www.boxcn.net/shared/g9h3f10fc0 http://ifile.it/km46pcl/catalyst.pdf |
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