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yexuqing木虫之王 (文学泰斗)
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【其他】軟性染料敏化太陽電池面臨的挑戰
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?????????????????R?????? 2010/8/26 [ [url= ocPrint(8807)]?? ?? ?? ?[/url] | ?? ?] ?? ?? ]???????????(Dye- sensitized Solar Cell; DSSC)?c????????????????????????Y???c?????????????????P????????????o??????u???O?伴?????a??????????D?QЧ????_??>11%???????M(10 cm ?? 10 cm)???D?QЧ????_>9%??????O?????????????????? ??????????????????? ???????u?????????????????????У????????(Metal Foil)????????????yTiO2?O???????Y???(450~500??C)?????TiO2?????w???g??TiO2?????w???c?????g?????????????????????????????????е???W??????s?????Toivola???^???N???I????????????????????l?F??????е??\???c??????????????Ч???~???????????????????????????????в??P??????????????P?????K????????????u???????????^????????????Kang????l??????TiO2?u?????P????(SUS 461)?????Ч?????2.1 %????????e??0.20 cm2?????????????P????(StSt)?ωT??SiOx??ITO??????ITO/SiOx/StSt?????????Ч????_??4.2%????????e??0.20 cm2?????M??????????W??????????????????t??????D?QЧ????????5.7%????????y?????SiOx????xITO????P?????????????^ITO?????P???a?????g?????????Grätzel?F?????30 nm??TiO2?????w????????W????g??TiO2?O?u???Ti??????????????TiCl4????????????????????Ч???_7.2%?? ??????????????l?????????O??????(Anodic Oxidation)?????????u???????????????Y??(TiO2 Tube)?????????????????D??????? ???TiO2???Y?????????f?C??(1D Transport)????σ?????????w???u????O??????C??(3D Random Walk)???D????????????????P?W???????????l???M???_?l/???|???S???u?似?g??????????????????????L?????????????c?u??r?g???????????????O??????????????u??TiO2???????????????????????Ч??????Ч?????????У??????W??S?????F?l?????????????/????????u?????????Ч?s???u??????TiO2???r?g??TiCl4????????????D?QЧ?????????7.6% ??  ?D????????TiO2?w??(3D Random Walk)?c????TiO2???Y??(1D Transport)???鹤???O??????f???D ???z???????????????? ???^?????????壬??????????????z??????????^??????????e?????????????ЙC?????????????????R???a??????(ITO)?????z????O?m???????????????????????塣????????z?????PET(poly(Ethylene Terephthalate))?cPEN(poly(Ethylene Naphthalate))????Y????D??????? PEN?cPET?????????W?Y????PEN???????h??????h?????????????????????PEN???е????????|????????PET???m?PEN?????c(Tm)???H???PET?s10??C??????????D????(Tg)?s???@??????????PET??78??C??????PEN ??120??C??????PEN?????????????????????????????????^?????r?????????????????????簲?????CTE (Coefficient of Thermal Expansion)?H18~20 ppm/??C????150??C?濾30?????????s?????0.005%???????PET?cPEN????????P??????^??D??????? ?????PET??PEN????????????200??C????????u??TiO2?O?o???????(450~500??C)???Y?u?????????????u????g?u????????????Y???TiO2 ?O?????_?l???????u??TiO2?O?c???????B?Y??????е????(Low- temperature Heating)?????(Compression)?????????(Microwave Irradiation)??????Y??(Hydrothermal Crystallization)?c?o??????????????W??????e(Chemical-vapor Deposition with UV Irradiation)??????У????TiO2?{?????????????????V??????????????????????TiO2?w?????{???m?????????????????cpH?????????????????????{????K????ù?T?u?????u??TiO2????????????????(100 MPa)????????????????????B?Y?????????Ч??????????(~80??C)????????}?????????????????????????????à??????????d??????????Y????????????и?????B?Y??????????????????D?????????z????????????_???Ч?????????????????? ????????????e??(Electrophoretic Deposition)???п??????????O?了?Σ???????u??TiO2?{?????c????????????u??????????????TiO2?O??????V?x?????z?w?u?????N????????????z?w????????B??????????????????У???????O????????У????O?g??????????????控???????????????????????????c????????????O???????????e???????γ??僌????D??????????σ???????c??????????????????  ?D???????????D ???????????/??????G???? ????????????I?????s?I284??????????Y??????http://www.materialsnet.com.tw/DocView.aspx?id=8758 |
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