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Zeolites are crystalline, hydrated aluminosilicates having micro- porous, regular structures. The zeolite micropores are of molecular size which give them adsorption, catalytic and ion exchange properties of paramount importance in both the chemical industrial field and the study of new applications related to process intensification [1], green chemistry [2], hybrid materials [3], medicine [4], animal food uses [5], optical and electrical based applications [6],reaction [7] and sensing [8] microsystems, and nanotechnology [9].Furthermore, the concept of zeolite can be extended to the so-called porous-tailored materials. This would include: oxide molecular sieves, porous coordination solids { such as metal organic frameworks (MOFs), or more specifically isoreticular MOFs (IRMORs), MMOFs (microporous MOFs) or porous coordination polymers(PCP) [10,11] } , porous carbons, sol¨Cgel-derived oxides, and porous heteropolyanion salts [12]. In consequence, the term zeolitic materials is frequently used in a very broad sense. This is the reason why even though this perspective is focused mainly on zeolites, mention to zeotypes and ordered mesoporous sieves will be done alone the paper. |
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