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Zeolites are crystalline, hydrated aluminosilicates having micro- porous, regular structures. The zeolite micropores are of molecular size which give them adsorption, catalytic and ion exchange properties of paramount importance in both the chemical industrial field and the study of new applications related to process intensification [1], green chemistry [2], hybrid materials [3], medicine [4], animal food uses [5], optical and electrical based applications [6],reaction [7] and sensing [8] microsystems, and nanotechnology [9].Furthermore, the concept of zeolite can be extended to the so-called porous-tailored materials. This would include: oxide molecular sieves, porous coordination solids { such as metal organic frameworks (MOFs), or more specifically isoreticular MOFs (IRMORs), MMOFs (microporous MOFs) or porous coordination polymers(PCP) [10,11] } , porous carbons, sol–gel-derived oxides, and porous heteropolyanion salts [12]. In consequence, the term zeolitic materials is frequently used in a very broad sense. This is the reason why even though this perspective is focused mainly on zeolites, mention to zeotypes and ordered mesoporous sieves will be done alone the paper. |
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gter_zhu(金币+21, 翻译EPI+1): 2010-08-29 20:07:33
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沸石是晶体，有微多孔，规则的结构的含水铝硅酸盐矿物质。微孔分子筛的分子大小赋予它们在化学工业领域都与有关过程强化[1]，绿色化学研究的新应用吸附，催化和离子交换的最重要的属性[2] [3杂化材料]，医学[4] 动物性食品使用[5]，光学和电子基础的应用[6]，反应[7]和传感[8]微技术和纳米技术[9]。此外，沸石的概念可以扩展到所谓的多孔量身定做的材料。 这将包括：氧化物分子筛，如金属有机骨架（MOFs），或更具体（IRMORs）isoreticular MOFs，多孔固体（协调， MMOFs（微孔MOFs）或多孔配位聚合物（PCP）的[10,11]），多孔炭，溶胶凝胶衍生氧化物，盐类和多孔杂多阴离子[12]。结果，沸石一词经常使用的材料是在一个非常广泛的意义。这就是为什么即使这观点主要集中在沸石，遑zeotypes有序介孔分子筛的原因将进行单独的文件。 |
2楼2010-08-27 16:33:00