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xiaoyezi8085

至尊木虫 (职业作家)

[交流] 【求助】审稿意见中的这些话是什么意思?

做的光解水制氢,审稿意见回来,只有一个,给的肯定意见,但感觉提的问题有点犀利,不太能确定,在此请教下大家。

1.A chemical reaction scheme showing catalyst synthesis would be helpful.  Also, balance all chemical reactions on this, and on the proposed photoreaction scheme。
这点是不是要求给个反应机制呢?还是什么
2.Figure 4 needs a more detailed caption, and arrows pointing to Cu3+/2+/++ should be given.  The XPS data is questionable since the fitting requires high resolution XPS.  Some data to show that they can resolve Cu3+/2+/1+ in a standard known sample would be helpful.
这句话是不是指有些文献可以拟合出,一二三价的铜在一个催化剂样品中,还是什么??审稿人的目的是什么?
3.In our own work in the area of hydrogen reduced catalysts, we became aware that stoichiometric (not catalytic) reactions are possible.  A rough calculation for the author's catalysts shows that about 850 -mole of reduced Cu-Ni is present in their 0.1 g catalysts.  Yields of H2 from water splitting need to be much higher overall than 850 -mole.  Thus, the question, how long do the catalysts live and what is the TOTAL  -moles H2 produced, compared with the -moles catalyst present?
这个计算是指什么计算呢?

欢迎大家指导交流。谢谢!

本文来自: 小木虫论坛 http://muchong.com/bbs/viewthread.php?tid=2311338&fpage=1
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sunboy3791

金虫 (正式写手)

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xiaoyezi8085(金币+1):谢谢参与
^_^@^_^(金币+1):多谢应助! 2010-08-19 15:25:53
第一条是建议你最好能给个机理图。第二个是让你表示出图中的铜的信号,要求xps的分辨率高一点。
2楼2010-08-19 13:05:53
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baozhutian

铜虫 (正式写手)

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xiaoyezi8085(金币+1):谢谢参与
liconglin970410(金币+1):多谢关注,欢迎常来交流 2010-08-20 09:52:54
需要用高分辨XPS图谱进行拟合分峰处理,判断不同价态的铜及含量。
3楼2010-08-19 16:39:11
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