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The attractive features of this ligand motif include pseudotetrahedral bonding geometry at phosphorus for increased steric shielding of the complexed metal relative to the planar central carbon present in the more familiar amidinato6 group and diminished predisposition toward aggregate formation with oxophilic metals by virtue of terminal sulfur (vs oxygen) substitution. |
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wypward(½ð±Ò+1):лл²ÎÓë 2010-06-06 10:28:04
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2Â¥2010-06-05 16:14:11
ddjasmine
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3Â¥2010-06-05 19:15:55
wang_xin
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4Â¥2010-06-05 20:27:53














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