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xuyewei1982(½ð±Ò+4):Íò·Ö¸Ðл 2010-06-03 19:25:18
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FN ISI Export Format VR 1.0 PT J AU Xu, YW Zhu, FH Xie, LQ Yang, JX Zhang, L Xie, RG AF Xu, Yewei Zhu, Fanghua Xie, Liqin Yang, Junxiao Zhang, Lin Xie, Rugang TI Synthesis and property studies of oligomer obtained from the reaction of 4-vinylbenzocyclobutene and styrene with divinyl tetramethyl disiloxane-bisbenzocyclobutene SO E-POLYMERS LA English DT Article ID NANOPARTICLES; DIENOPHILES; MONOMERS AB Radical copolymerization of 4-vinylbenzocyclobutene (VBCB) with styrene (St) afforded the copolymer (4-vinylbenzocyclobutene-co-styrene) (VBCB-St). Reaction of VBCB-St and divinyl tetramethyl disiloxane-bisbenzocyclobutene (DVSBCB) gave the oligomer (VBCB-St-DVSBCB), which was subsequently subjected to the cure reaction. The structures of VBCB-St and oligomer (VBCB-St-DVSBCB) were characterized by FTIR and H-1 NMR, which are in agreement with the proposed structures. Molecular weights of the synthesized polymers were estimated by gel permeation chromatography (GPC). Differential scanning calorimetry (DSC) showed that VBCB-St exhibited glass transition temperature (T-g > 95 degrees C) however it is not the case for the oligomers (VBCB-St-DVSBCB). TG measurements indicated that the polymers had the good thermal stability with decomposition temperatures (T-D > 370 degrees C). The polymer resin possessed good film planarization in the AFM images and the process of oligomer curing on a wafer without fusion and flow. These results indicated that the oligomer (VBCB-St-DVSBCB) is a promising film material with a relatively low cost. C1 [Xu, Yewei; Xie, Liqin; Yang, Junxiao] SW Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China. [Xu, Yewei; Zhu, Fanghua; Zhang, Lin] China Acad Engn Phys, Res Ctr Laser Fus, Mianyang 621900, Sichuan, Peoples R China. [Xie, Rugang] Sichuan Univ, Dept Chem, Chengdu 610064, Sichuan, Peoples R China. RP Yang, JX, SW Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China. EM yangjunxiao@swust.edu.cn zhlmy@sina.com FU National Nature Science Foundation of China [NSFC20574046] FX We are grateful to the National Nature Science Foundation of China (NSFC20574046) for supporting this research. NR 15 TC 0 PU EUROPEAN POLYMER FEDERATION PI STRASBOURG PA 1, QUAI LEZAY-MARNESIA, F067000 STRASBOURG, FRANCE SN 1618-7229 J9 E-POLYMERS JI e-Polymers PD FEB 10 PY 2010 AR 013 PG 8 SC Polymer Science GA 558OW UT ISI:000274755100001 ER ×îÏÂÃæµÄÕâ´®Êý×Ö¾ÍÊÇÁË [ Last edited by lxj_zk on 2010-6-3 at 18:07 ] |
4Â¥2010-06-03 18:00:52













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