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.   Accession number:  20101612863225

Title:  Preparation of TiO2-g-Polystyrene Nanosphere and Its Application in Toughening PS Matrix

Authors:  Sang, Xiaoming1 ; Wu, Peng1 ; Hou, Guixiang1 ; Yu, Shouwu1  

Author affiliation:  1  Hebei Province Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering, Hebei Polytechnic University, TangShan, Hebei, 063009, China


Corresponding author:  Sang, X. (xmsang@heut.edu.cn)  

Source title:  Advanced Materials Research

Abbreviated source title:  Adv. Mater. Res.

Volume:  97-101

Monograph title:  Manufacturing Science and Engineering I

Issue date:  2010

Publication year:  2010

Pages:  1677-1680

Language:  English

ISSN:  10226680

ISBN-10:  0878492801

ISBN-13:  9780878492800

Document type:  Conference article (CA)

Conference name:  2009 International Conference on Manufacturing Science and Engineering, ICMSE 2009

Conference date:  December 26, 2009 - December 28, 2009

Conference location:  Zhuhai, China

Conference code:  79909

Sponsor:  University of Wollongong (UOW); Hong Kong Industrial Technology Research Centre (ITRC)

Publisher:  Trans Tech Publications, P.O. Box 1254, Clausthal-Zellerfeld, D-38670, Germany

Abstract:  TiO2-g-Polystyrene(PS) nano-microspheres were prepared by grafted styrene monomer on the surface of nano-TiO2 particles via emulsion polymerization, and its surface and morphology were studied by Transmission electron microscopes(TEM), Fourier transform infrared spectroscopy(FTIR) and thermal gravimetric analysis(TGA). The results showed that the TiO2-g-PS nano-microsphere had a structure of sphericity composed of TiO2 and PS as core and shell respectively. The core-shell nanoparticles were subsequently used as filler in a PS matrix, and the impact strength of the TiO2-g-PS/PS composites were studied. The results showed that the impact strength of the composite material could be improved obviously, the maximum value of impacted strength of the TiO 2-g-PS/PS was 1.75kJ/m2, which was 180% higher than that of pure PS. Drawing from the results, it could be confirmed that these core-shell TiO2-g-PS nanosphere fillers could toughen the PS matrix. © (2010) Trans Tech Publications.

Number of references:  11

Main heading:  Impact strength

Controlled terms:  Composite micromechanics  -  Electron microscopes  -  Emulsification  -  Emulsion polymerization  -  Fillers  -  Fourier transform infrared spectroscopy  -  Microspheres  -  Nanospheres  -  Polymers  -  Polystyrenes   -  Shells (structures)  -  Styrene  -  Thermogravimetric analysis  -  Transmission electron microscopy

Uncontrolled terms:  Core-shell  -  Core-shell nanoparticles  -  matrix  -  Maximum values  -  Nano-TiO  -  Styrene monomer  -  Thermal gravimetric analysis  -  TiO  -  Transmission electron microscope

Classification code:  815.1 Polymeric Materials  -  815.1.1 Organic Polymers  -  815.2 Polymerization  -  818 Rubber and Elastomers  -  812.3 Glass  -  921.4 Combinatorial Mathematics, Includes Graph Theory, Set Theory  -  931.1 Mechanics  -  932 High Energy Physics; Nuclear Physics; Plasma Physics  -  933 Solid State Physics  -  931 Classical Physics; Quantum Theory; Relativity  -  812.1 Ceramics  -  421 Strength of Building Materials; Mechanical Properties  -  741.3 Optical Devices and Systems  -  761 Nanotechnology  -  801 Chemistry  -  408.2 Structural Members and Shapes  -  801.3 Colloid Chemistry  -  803 Chemical Agents and Basic Industrial Chemicals  -  804.1 Organic Compounds  -  804.2 Inorganic Compounds  -  802.3 Chemical Operations

DOI:  10.4028/www.scientific.net/AMR.97-101.1677

Database:  Compendex

   Compilation and indexing terms, © 2009 Elsevier Inc.
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