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20054937

铁杆木虫 (著名写手)

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A facile chemical polymerization method was applied to prepare LiFePO4/C-PPy composite using
Fe(III)tosylate as oxidant. The as-prepared LiFePO4/C-PPy sample with PPy content of approximately
4 wt% showed great rate capability with a discharge capacity of 115 mAh/g at 20C. High temperate
cycling performance of the LiFePO4/C-PPy sample was compared with bare LiFePO4/C at 5C charge–discharge
rate at 55 C. The LiFePO4/C-PPy cathode showed superior cycling stability with an initial capacity
of 155 mAh/g. Ninety percentage of this initial capacity was retained after 300 cycles, compared to 40% of
that of bare LiFePO4/C. The LiFePO4/C-PPy electrode showed stable discharge plateau voltage of 3.35–
3.25 V vs. Li+/Li during long term cycling. The superior performance of the LiFePO4/C-PPy electrode
was due to the enhanced electrical conductivity, negligible iron dissolution and alleviated electrode
cracking contributed by PPy coating.

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hzh19860327

金虫 (小有名气)

20054937(金币+100, 翻译EPI+1):谢谢 2010-04-20 11:19
以对苯磺酸铁(Ⅲ)为氧化剂,通过简便的化学聚合方法制备LiFePO4/C-PPy复合材料。聚吡咯含量为4%的LiFePO4/C-Ppy在20° C时具有较大放电容量(115 mAh/g)。在55 ° C,5C倍率充放电量时, LiFePO4/C-Ppy有比LiFePO4/C更稳定的循环性能。LiFePO4/C-PPy阴极的电容量为1155 mAh/g,并表现出优良的循环稳定性能。LiFePO4/C-PPy在经过300个循环周期后LiFePO4/C-PPy保留了90%的初始电容量,而LiFePO4/C只保留了40%。与Li+/ Li电极相比,LiFePO4/C-Ppy电极在长时间的循环中表现出更加稳定的放电平台电压,其电压变化范围在3.35-3.25 v之间。LiFePO4/C-PPy具有优越电极性能,是由于 PPy 涂层增强了电极的导电性,减少了铁离子的溶解同时又减轻乐涂层开裂这种现象。
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