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zyhou

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[交流] 【资源】化物所又发Science文章了已有20人参与

大连化物所的科学家又在Science上发表了新作。
http://www.sciencemag.org/cgi/reprint/327/5972/1501.pdf

摘要:Partial wave resonances, quasi-bound resonance states with well-defined rotation in the transition state region of a chemical reaction, play a governing role in reaction dynamics but have eluded direct experimental characterization. Here, we report the observation of individual partial wave resolved resonances in the F + HD → HF + D reaction by measuring the collision energy–dependent, angle- and state-resolved differential cross section with extremely high resolution, providing a spectroscopic probe to the transition state of F + HD → HF + D. The agreement of the data with the high-level theoretical calculations confirms the sensitivity of this
probe to the subtle quantum mechanical factors guiding this benchmark reaction.
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